Doping potassium ions in silver cyanide complexes for green luminescence.

Doping potassium ions in silver cyanide complexes for green luminescence.
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在氰化银络合物中掺杂钾离子以产生绿色发光。

DOI:
10.1039/c3dt53219d
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发表时间:
2014-02
影响因子:
4
通讯作者:
Huang, Kun-Lin
Huang, Kun-Lin
中科院分区:
化学2区
文献类型:
--
作者:
Liu, Xi;Li, Lin;Yang, Yun-Zhi;Huang, Kun-Lin

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在银络合物中掺杂钾离子导致两种异金属银-氰化钾络合物,即[Me 4 N]2[KAg 3(CN)6](1),其具有典型的NaCl型骨架,包含不同的配体-未支撑的亲银相互作用,和[Ag 3(H2O)3][K(CN)2]3(2),其具有前所未有的3-D(4,4,6,6)由独特的[Ag_3(H_2 O)_3]团簇连接凹凸[K(CN)_2]层形成的-连接骨架。这两种配合物均表现出绿色发光,并通过密度泛函理论分析研究了它们的结构与光致发光的关系,以及钾离子掺杂对发光的调控作用。
Doping potassium ions in silver cyanide complexes leads to two heterometallic silver-potassium cyanide complexes, namely, [Me4N]2[KAg3(CN)6] (1) with a typical NaCl-type framework containing distinct ligand-unsupported argentophilic interactions, and [Ag3(H2O)3][K(CN)2]3 (2) with an unprecedented 3-D (4,4,6,6)-connected framework formed by unique [Ag3(H2O)3] clusters connecting concave-convex [K(CN)2] layers. The two complexes exhibit green luminescence, and the relationships between their structures and photoluminescence, as well as the regulating effect on the luminescence by doping of potassium ions are well investigated via density functional theory analysis.
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