Half-Collision Scattering in van der Waals Complexes

这项研究是实验物理化学的一部分， 程序，是为了研究货车der的动力学而设计的 Waals复合体 该计划的结果将有助于 理解松散结合的结合和动力学 化学复合物 将进行一系列实验来研究 氮稀有气体货车范德华振动预离解 在国家层面上的合作。 双共振激光器 方法将被用来确定时间演变的 单分子离解过程和内部 新生光产物的振转态分布。 氮产品的最终旋转分布将 反映了分子间势沿着的各向异性 反应坐标。

This research, part of the Experimental Physical Chemistry Program, is designed to investigate the dynamics of van der Waals complexes. The results of this program will be useful in understanding the bonding and dynamics of loosely bound chemical complexes. A series of experiments will be performed to study the vibrational-predissociation of nitrogen rare gas van der Waals complexes at the state-to-state level. Double resonance laser methods will be used to determine the time evolution of the unimolecular dissociation process and the internal ro-vibrational state distribution of the nascent photoproducts. The final rotational distribution of the nitrogen product will reflect the anisotropy of the intermolecular potential along the reaction coordinate.