Investigation of Bridged Organometallic Complexes on Metal Oxide Supports
Investigation of Bridged Organometallic Complexes on Metal Oxide Supports
批准号:
9014260
负责人:
Eric Mintz
金额:
$17.98万
依托单位:
依托单位国家:
美国
项目类别:
Standard Grant
财政年份:
1990
资助国家:
美国
项目状态:
已结题
起止时间:
1990-09-01 至 1994-02-28
中文摘要
少数民族机构研究改进(RIMI) 该项目将探索金属氧化物的化学 含桥联环戊二烯基的负载型配合物 和羰基配体。 调查人员还将 重新审查五甲基溴金属的使用 复合物作为活化小分子的试剂 分子。 调查人员在以下方面经验丰富: 配体和金属配合物的合成及红外光谱 这一过程中涉及的技术。 的 载体的制备与表征 有机金属配合物是最先进的 多相催化领域的研究。 本文全面考察了有机金属化合物 将大大提高研究能力的一个 主要是少数民族机构,并将提供 创新的科学技术,以学生在他们的 专业发展。
英文摘要
This Research Improvement in Minority Institutions (RIMI) project will explore the chemistry of metal oxide supported complexes containing bridged cyclo-pentadienyl and carbonyl ligands. The investigators will also reexamine the use of pentamethylcyclopentadienyl metal complexes as reagents for the activation of small molecules. The investigators are experienced in the synthesis of ligands and metal complexes and the infrared techniques that are involved in the process. The preparation and characterization of supported organometallic complexes are at the cutting edge of research in the area of heterogeneous catalysis. This comprehensive investigation organometallic compounds will significantly increase the research capability of a predominantly minority institution and will provide innovative scientific techniques to its students in their professional development.
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