Architecture and Properties of Polymer Systems

本文的工作包括：(1)互穿网络聚合物的合成、表征、微观结构、电导率及其形成和性质的计算机模拟，(2)模板对共聚反应的影响，(3)用有偏抽样蒙特卡罗模拟方法研究聚合物的动态松弛时间；(4)大的静态或动态各向异性对聚合物体系的影响。在每一个主题中，他们都将强调聚合物结构和异构性(包括拓扑异构性)的影响。这项研究是一项理论和实验相结合的项目，旨在将物理性质与聚合物的分子结构联系起来。

This research consists of work on: (1) Interpenetrating polymer networks-their synthesis, characterization, microstructure, electrical conductivity of iodine-doped samples and the computer simulation of their formation and properties; (2) Template effects on copolymerization; (3) The study of polymer dynamical relaxation times by biased sampling Monte Carlo simulations; and (4) The effects of large static or dynamically induced anisotropy on polymer systems. In each of these topics they will stress the influence of polymer architecture and isomerism (including topological isomerism). This research is a combined theoretical and experimental project designed to relate physical properties with the molecular architecture of polymers.