Purchase of Superconducting High-Field FT-NMR Spectrometer

9311730赖特 化学研究仪器计划的这个奖项 将协助犹他州的化学系 大学在购买高分辨率400 MHz， 多核核磁共振（NMR）光谱仪。 这一升级将大大加强一些领域的研究 其中包括： 1)非线性光学聚合物的新方法和新进展 催化反应，2）铑催化的羰基化合物的硅烷化，3）含有羰基化合物的络合物的反应性， 亚硝酰基环戊二烯基钌核，4）通过Diehls-Alder方法合成含二芳基醚α-氨基酸的环肽，5）合成杂环化合物的新方法，6）气单胞菌功能的NMR研究 氨肽酶，7）使用氨基肽酶表征新的锌和镉络合物， NMR，8）有机离子自由基和双电荷离子的反应。 %%% 核磁共振（NMR）光谱仪用于 获得有关分子结构的信息（什么类型的 存在碳和/或氢原子和/或杂原子， 每种类型的原子的相对数量是多少， 它们在分子中相互连接）和分子 动力学（分子的各个部分有多快 移动）。 这项文书对于任何有意义的、 现代合成化学研究计划 ***

9311730 Wright This award from the Chemistry Research Instrumentation Program will assist the Department of Chemistry at Utah State University in the purchase of a high resolution 400 MHz, multinuclear, nuclear magnetic resonance (NMR) spectrometer. This upgrade will enhance greatly research in a number of areas including the following: 1) Novel approaches to nonlinear optical polymers and new catalytic reactions, 2) Rhodium catalyzed silaformylation of carbonyl compounds, 3) Reactivity of complexes containing the nitrosylcyclopentadienylruthenium core, 4) Synthesis of cyclic peptides containing diaryl ether alpha- amino acids via Diehls-Alder methods, 5) New methods for the synthesis of heterocyclic compounds, 6) NMR investigations into the function of Aeromonas aminopeptidase, 7) Characterization of new zinc and cadmium complexes using NMR, 8) Reactions of organic ion radicals and doubly charged ions. %%% A nuclear magnetic resonance (NMR) spectrometer is used to obtain information about molecular structure (what types of carbon and/or hydrogen atoms and/or hetero-atoms are present, what are the relative number of each type of atoms and how are they connected to one another in the molecule) and molecular dynamics (how rapidly are the various parts of the molecule moving). This instrument is essential for any meaningful, modern synthetic chemistry research program. ***