New Chemistry of Bimetallic Fischer Carbene Complexes

9313746 Finn本研究的重点是开发含有附加的、缺电子的、连接到卡宾杂原子的金属中心的Fischer卡宾络合物的化学。 第二个金属中心用于提高络合物的反应性，并充当卡宾和底物部分的组织模板，导致选择性转化。 还将探讨催化卡宾转移的试剂的潜力。 %有了这个更新的奖项，合成有机计划正在支持博士的研究。弗吉尼亚大学化学系的芬恩说。 芬恩教授将把他的工作重点放在Fischer络合物的化学上，卡宾络合物与碳-碳双键和三键进行各种各样的反应。 ***

9313746 Finn The focus of this research is the development of the chemistry of bimetallic Fischer carbene complexes containing an added, electron deficient, metal center attached to the carbene heteroatom. The second metal center serves to heighten the reactivity of the complexes and acts as a template for the organization of the carbene and substrate moieties leading to selective transformations. The potential of the reagents for catalytic carbene transfer will also be explored. %%% With this renewal award, the Synthetic Organic Program is supporting the research of Dr. M.G. Finn of the Department of Chemistry at the University of Virginia. Professor Finn will focus his work on the chemistry of Fischer complexes, carbene complexes that that engage in a wide variety of reactions with carbon-carbon double and triple bonds. ***