Solid State Coordination Chemistry of Metal Oxide Hybrid Materials

锡拉丘兹大学的Jon A.Zubieta教授在无机化学、生物无机化学和金属有机化学项目的支持下，探索在水热介质中合成杂化金属氧化物晶体。这些金属氧化物能够在其晶相中结合有机成分，因此该项目的设计和发现方面详细阐述了对结构决定因素对新型氧钒和氧钼磷酸盐及其相关材料的热稳定性和孔尺寸的作用的理解。这些材料的微孔特性在分离和气体储存、催化和非线性光学方面具有重要的应用价值。本科生和研究生将参与这项跨学科的研究，进行拟议的化学合成和性质测量。Zubieta教授将为研究生开发为期两个学期的x射线结晶学和结构固态化学的教学材料，以及一个关于结晶学原理的网站。这些教学材料已被改编，用于向参加锡拉丘兹大学先期项目的高中教师和学生介绍。

Professor Jon A. Zubieta of Syracuse University is supported by the Inorganic, Bioinorganic and Organometallic Chemistry Program to explore the synthesis of hybrid metal oxide crystals in hydrothermal media. These metal oxides are capable of incorporating organic components in their crystalline phases and thus the design and discovery facets of the project elaborate on the understanding of the role of structural determinants on thermal stability and pore dimensions of the novel oxovanadium and oxomolybdenum phosphonates and related materials. The microporous properties of these materials are of considerable interest for applications in separation and gas storage, catalysis, and non-linear optics. Undergraduate and graduate students will be involved in this interdisciplinary research, conducting the proposed chemical syntheses and property measurements. Professor Zubieta will develop instructional materials for graduate students in the form of a two-semester sequence devoted to x-ray crystallography and structural solid state chemistry as well as a website on crystallographic principles. These instructional materials have been adapted for presentation to high school teachers and students participating in the Syracuse University Project Advance.