Design and synthesis of organic materials for energy storage, optoelectronic applications and as templates for novel types of nanotubes

这项拟议研究的目标是设计和合成用于储能、光电应用和作为新型纳米管模板的有机材料。在第一个子项目中，将开发有机小分子和聚合物作为电池电极材料。这将通过合成氧化还原活性分子来实现，这些活性分子将被整合到聚合物结构中。第二个子项目的目标是合成低聚物和聚合物，其中共轭是通过螺环中心介导的。由于所得材料的三维结构，薄膜具有很高的稳定性。发射特性可以通过改变螺环单元来调节。在第三个子项目中，将合成可作为新型纳米管模型系统的共轭纳米带。这些环状化合物具有很高的主客体相互作用、作为活性器件材料和功能表面图案化的潜力。

The goal of the proposed research is the design and synthesis of organic materials for energy storage, for optoelectronic applications, and as templates for novel types of nanotubes. In the first sub-project organic small molecule and polymeric compounds will be developed as electrode materials for batteries. This will be achieved by synthesizing redox active molecules that will be incorporated into polymer architectures. The goal of the second sub-project is the synthesis of oligomers and polymers, in which conjugation is mediated through spiro centers. Due to the threedimensional structure of the resulting materials high stabilities are expected in thin film. The emission properties can be tuned by variation of the spiro units. Within the third sub-project conjugated nanobelts will be synthesized that can serve as model systems for novel types of nanotubes. These cyclic compounds have high potential for host-guest interactions, as active device materials, and for functional surface patterning.