CAREER: Fast-Rate Manufacturing of Thermoplastic Polymer Composites with Tailored Microstructure and Performance

该学院早期职业发展（CAREER）补助金将支持有助于开发具有增强性能的高性能热塑性复合材料的快速制造的研究，促进美国制造科学和技术。高性能热塑性复合材料正在工业中出现，以取代金属，因为这些复合材料提供重量轻，出色的机械性能，化学稳定性和通过热成型在几分钟内可制造性。然而，在具有高冷却速率的快速工艺中，聚合物没有足够的时间形成长链有序（晶体），这反过来降低了结晶度水平。高结晶度是改善刚度和强度所必需的;然而，较低的结晶度是改善韧性所期望的。这些竞争性质可以通过控制聚合物的详细结构来优化。这项资助支持基础研究，填补了在加工过程中设计热塑性复合材料结晶度所需的知识空白，以同时实现高刚度，强度和韧性。纳米材料（NM）用于控制结晶度，而不使用有害溶剂，促进可扩展性。该研究加速了下一代复合材料的制造，减轻了重量，提高了强度和韧性，通过为美国汽车，航空航天和海洋工业提供可扩展的快速制造技术，使美国经济和国家安全受益。这项研究的跨学科性质为培养下一代STEM领域的高技能工程师和科学家提供了独特的机会，特别是从女性和代表性不足的少数群体中培养，这进一步增强了美国制造业劳动力的多样化。在快速制造半结晶聚合物复合材料过程中实现的优化复合材料机械性能需要工程设计结晶形态。这项研究将使在复合材料加工过程中，在多个长度尺度上定制半结晶复合材料的微观结构的替代能力。由纤维素纳米颗粒-石墨烯纳米片组成的纳米材料用于协同增强和创建分层晶体结构。该项目将产生新的信息，弥合知识差距的结晶-非晶域从分子键和力的演变，他们的翻译界面和层间性能，以及他们的变形下的服务负载。本研究利用X射线散射和原位显微镜，辅以密度泛函理论和分子动力学模拟，以建立分子相互作用-半结晶微结构-性质的关系。该研究还解决了从分子键离解到分层的损伤转化问题。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

This Faculty Early Career Development (CAREER) grant will support research that contributes to the development of fast-rate manufacturing of high-performance thermoplastic composites with enhanced properties, promoting the US manufacturing science and technology. High-performance thermoplastic composites are emerging in industries to replace metals as these composites offer light weighting, outstanding mechanical properties, chemical stability, and manufacturability within few minutes via thermoforming. However, in fast-rate processes with high cooling rates, there is not sufficient time for the polymer to form long chain orders (crystals) that in turn reduces the crystallinity level. High crystallinity is required for improved stiffness and strength; however, lower crystallinity is desirable to improve toughness. These competing properties can be optimized by control of the detailed structure of the polymer. This grant supports fundamental research that fills the knowledge gap needed to engineer the thermoplastic composite crystallinity during processing to achieve concurrently high stiffness, strength and toughness. Nanomaterials (NMs) are used to control the crystallinity without the use of hazardous solvents, promoting the scalability. The research accelerates the manufacturing of next generation of composites with reduced weight and increased strength and toughness that benefits the US economy and national security by equipping U.S. automotive, aerospace and marine industries with a scalable and fast-rate manufacturing technique. The interdisciplinary nature of this research provides unique opportunities to train the next generation of highly skilled engineers and scientists in STEM fields especially from women and underrepresented minority groups that further enhances the diversification of the US manufacturing workforce.Optimized composite mechanical properties achieved during fast-rate manufacturing of semicrystalline polymer composites require engineering the crystalline morphology. This research will enable alternative capabilities in tailoring the microstructure of semicrystalline composites at multiple length scales during composite processing. Nanomaterials consisting of cellulose nanocrystals-graphene nanoplatelets are used to synergistically reinforce and create a hierarchical crystalline architecture. This project will generate new information by bridging the knowledge gap in the evolution of crystalline-amorphous domains from molecular bonds and forces, their translation to interfacial and interlaminar properties, and their deformation under service load. The research uses in-operando X-ray scattering and in-situ microscopy complemented by density functional theory and molecular dynamics simulations to establish the molecular interactions-semicrystalline microstructure-property relationship. The research also addresses the damage transformation from molecular bonds dissociation to delamination.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.