Exploratory Chemistry of Molybdenum and Tungsten Fluorides

总之，我们提出了钼和钨氟化物及其相关化合物的探索化学。主要目标是合成新颖的无机化合物或Mo和W氟化物、氮氟化物和氟氧化物的络合物。研究了它们在无水HF、氨和二氧化硫中的水解和氨解反应，以及它们与叠氮化物、氰化物、硫氰酸盐和酰胺的刘易斯酸碱反应。热分解研究将显示是否可以获得其他氮化物、氮氧化物、碳氮化物等。

In summary we propose exploratory chemistry of Mo and W fluorides and their related compounds. Major goals are the synthesis of novel inorganic compounds or complexes of Mo and W fluorides, nitride fluorides, and oxyfluorides. Hydrolysis and ammonolysis reactions of these are to be investigated in anhydrous HF, ammonia and sulfur dioxide, as well as their Lewis acid-base reactions with azides, cyanides, thiocyanates and amides. Thermal decomposition studies will show if other nitrides, oxynitrides, carbonitrides, …, can be obtained.