Nonlinear Infrared Short-Time Spectroscopy for the Characterization of Fluorine-Specific Interactions: Structure, Dynamics and Catalytic Determinants of H∙∙∙F-Networks on Fluorido Complexes and Metallo-peptides (A09*)

在项目A9N中|Horch，超快和非线性二维红外光谱和量子化学计算被用来阐明和量化氟特异性相互作用的结构和动力学方面。重点是在催化金属中心的配位领域的相互作用，特别是涉及含氟反应物或氟化配体系统的氢键。此外，氟特异性的相互作用的肽与氟化氨基酸的金属配合物被阐明。

In project A9N|Horch, ultrafast and nonlinear 2D infrared spectroscopy and quantum chemical calculations are used to elucidate and quantify structural and dynamic aspects of Fluorine-Specific interactions. The focus is on interactions in the coordination sphere of catalytic metal centers, particularly hydrogen bonds involving fluo-rine-containing reactants or fluorinated ligand systems. Furthermore, Fluorine-Specific interactions in metal complexes of peptides with fluorinated amino acids are elucidated.