Exploration of Purely Organic Mole cular Metal Based on Hydrogen-Bond and Charge-Transfer Interaction

为了探索基于氢键和电荷转移相互作用而表现出特殊性质和多功能的纯有机分子金属，我们设计并合成了由四硫富瓦烯类似物和咪唑、碱基等氢键基团组成的新型电子给体分子。这些新分子通过强健的氢键形成不同的网络结构，与有机电子受体分子形成高导电性的电荷转移络合物。

In order to explore purely organic molecular metals exhibiting peculiar properties and multiple functions based on the cooperation of hydrogen-bond and charge-transfer interactions, we have designed and synthesized new electron-donor molecules composed of tetrathiafulvalene analogues and hydrogen-bonding groups such as imidazole and nucleobases. These new molecules formed diverse network structures by robust hydrogen-bonds, and achieved highly conducting charge-transfer complexes with organic electron-acceptors molecules.