DevelopmentandFunctionalizationofSupramolecularComplexofπ-ConjugatedMacrocyclesandDNA

我尝试开发由π偶联的大环分子与脱氧核糖核酸组成的超分子络合物，以期显示出新的功能性质。π-共轭大环由苯乙炔基团连接烷氧基链组成，在不同的有机溶剂中溶解。在π-共轭大环的内部，由于酯基可以转变为可与醇胺基团进行各种反应的碳酸，所以酯部分被取代。据我们所知，这是关于π共轭大环内含酯基团的苯乙炔部分的第一个报告。π共轭大环在溶液和固体之间表现出荧光行为。

I attempt the development of supramolecular complexes composed of π-conjugated macrocyclicmolecules and DNA, which are expected to exhibit the new functional properties. π-Conjugatedmacrocycle composes of phenylacetylene moieties tethering alkoxy chains to be dissolved invarious organic solvents. In the inner of π-conjugated macrocycle, ester moieties are substitutedbecause an ester group can turn into the carbonic acid available for various reactions with alcoholamine group. To the best of our knowledge, this is the first report on the π-conjugated macrocyclecontaining phenylacetylene moieties having ester groups at the inner position. π-Conjugatedmacrocycle shows fluorescent behavior between in the solution and in the solid states.