Spin centers in molecular solids - from paramagnetic salts to organic conductors (C05)

为了克服在我们的基于TTF的电荷转移（CT）盐中的分离堆叠内广泛观察到的对形成，设想了使用金刚石砧座单元的高压实验和使用更强的相互作用供体如BEDT-TTF和硒衍生物TMTSeF。一系列未开发的，甚至尚未合成的富电子低氧化电位的分子将被探测作为新的CT复合物的供体。我们将开始探索碱掺杂的无溶剂多环芳烃的性质，因为最近在这类化合物中声称具有显着的物理性质，如超导性。

To overcome the widely observed pair formation within the segregated stacks in our TTF based charge transfer (CT) salts, high pressure experiments with diamond anvil cells and the use of stronger interacting donors like BEDT-TTF and the selenium derivative TMTSeF are envisaged. A series of unexplored and even not yet synthesized electron rich molecules with low oxidation potentials will be probed as donors in new CT complexes. We will start to explore the properties of alkali doped solvent-free polycyclic aromatic hydrocarbons since remarkable physical properties like superconductivity have recently been claimed among this class of compounds.