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C-H to C-F using electrochemistry and gold catalysis

C-H to C-F using electrochemistry and gold catalysis
使用电化学和金催化将 C-H 转化为 C-F
批准号:
DP200100013
负责人:
Prof Jason Dutton
金额:
$26.0万
依托单位:
依托单位国家:
澳大利亚
项目类别:
Discovery Projects
财政年份:
2020
资助国家:
澳大利亚
项目状态:
已结题
起止时间:
2020-01-01 至 2024-12-31

项目摘要

项目成果

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中文摘要
翻译
金在化学催化方面具有巨大的潜力,该项目将利用CIs发现的一类令人着迷的新型金化合物来开发新型催化剂。利用这种化学反应可以制备一系列含氟配体的金(III)化合物。然后将探索这些分子的催化特性,特别侧重于为芳烃增加价值。该项目的最终目标是开发新的催化剂,用于形成碳氟键和有机的选择性氟化
英文摘要
Gold offers great potential in chemical catalysis and this project will use a fascinating new class of gold compounds discovered by the CIs, to develop novel catalysts. Using this chemistry a series of gold(III) compounds with fluoride ligands will be prepared. The catalytic properties of these molecules will then be explored, with a particular focus on adding value to arene hydrocarbons. The ultimate goal of the project is development of new catalysts for the formation of carbon-fluorine bonds and the selective fluorination of organic compounds. Fluorinated organic molecules are of critical importance in medicinal chemistry and new catalysts of this type offers the potential for better synthesis of medicines and diagnostic agents.
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Discovering new organic chemistry using an inorganic touch
  • 批准号:
    FT160100007
  • 项目类别:
    ARC Future Fellowships
  • 资助金额:
    $56.36万
  • 财政年份:
    2017
  • 负责人:
    Prof Jason Dutton
  • 依托单位:
Base stabilised dicarbon as a new building block for supramolecular organometallic chemistry
  • 批准号:
    DE130100186
  • 项目类别:
    Discovery Early Career Researcher Award
  • 资助金额:
    $27.36万
  • 财政年份:
    2013
  • 负责人:
    Prof Jason Dutton
  • 依托单位:
海外基金