CONTROL OF DIELS ALDER REACTIONS BY SURFACTANT BASED ORGANIZED MEDIA

该项目的目标是使用胶束和囊泡 基于官能化表面活性剂的体系，用于控制 Diels-Alder反应的区域选择性。世界上最重要的一部分 该项目涉及新型离子化合物的合成和表征 含有1，3-二烯和亲二烯组分的表面活性剂 迪尔斯-阿尔德系统。特征描述通常包括低和 利用快原子轰击进行高分辨质谱分析 (FAB)电离。我们的许多表面活性剂不服从于 燃烧分析。因此，表面活性物质的高分辨率测量 离子能提供燃烧分析所不能提供的成分证明。

The objective of this project is to use micellar and vesicular systems, based on functionalized surfactants, for control of the regioselectivity of Diels-Alder reactions. A major part of the project involves the synthesis and characterization of novel ionic surfactants containing the 1,3-diene and dienophile components of the Diels-Alder systems. Characterization often includes both low and high resolution mass spectral analysis utilizing fast atom bombardment (FAB) ionization. Many of our surfactants are not amenable to combustion analysis. Thus high resolution measurements of surfactant ions provides proof of composition that combustion analysis cannot.