Overtone mobility spectrometry: part 3. On the origin of peaks.

Overtone mobility spectrometry: part 3. On the origin of peaks.
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DOI:
10.1007/s13361-011-0087-y
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发表时间:
2011-05
影响因子:
3.2
通讯作者:
Clemmer, David E.
Clemmer, David E.
中科院分区:
化学3区
文献类型:
--
作者:
Valentine, Stephen J.;Kurulugama, Ruwan T.;Clemmer, David E.

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通过离子轨道模拟研究了泛频迁移谱(OMS)中非整数泛频峰的来源。模拟结果表明,这些OMS功能来自高阶泛音系列。作为一种手段,描述的峰的位置的图解推导公式。新的方程使得从任何OMS峰确定碰撞截面成为可能。此外,它被扩展为预测OMS分布中任何峰的分辨能力的手段。
The origin of non-integer overtone peaks in overtone mobility spectrometry (OMS) spectra is investigated by ion trajectory simulations. Simulations indicate that these OMS features arise from higher-order overtone series. An empirically-derived formula is presented as a means of describing the positions of peaks. The new equation makes it possible to determine collision cross sections from any OMS peak. Additionally, it is extended as a means of predicting the resolving power for any peak in an OMS distribution.
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