Fabrication of nickel and nickel carbide thin films by pulsed chemical vapor deposition

Fabrication of nickel and nickel carbide thin films by pulsed chemical vapor deposition
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脉冲化学气相沉积法制备镍和碳化镍薄膜

DOI:
10.1557/mrc.2018.21
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发表时间:
2018-03
期刊:
影响因子:
1.9
通讯作者:
Wang Xinwei
Wang Xinwei
中科院分区:
材料科学4区
文献类型:
--
作者:
Guo Qun;Guo Zheng;Shi Jianmin;Sang Lijun;Gao Bo;Chen Qiang;Liu Zhongwei;Wang Xinwei

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我们报道了一种新的脉冲化学气相沉积(PCVD)工艺,用于沉积镍(Ni)和碳化镍(Ni3Cx)薄膜。该工艺使用双(1,4 - 二叔丁基 - 1,3 - 二氮杂丁二烯基)镍(II)前驱体,并以H₂气体或H₂等离子体作为共反应物,在……温度下(句子不完整,最后一个单词“at a tem”应为“at a temperature”,但此处未给出具体温度数值)。
We report a new pulsed chemical vapor deposition (PCVD) process to deposit nickel (Ni) and nickel carbide (Ni3Cx) thin films, using bis(1,4-ditert- butyl-1,3-diazabutadienyl)nickel(II) precursor and either H_2 gas or H_2 plasma as the coreactant, at a temperature from 140 to 250 °C. All the PCVD films are fairly pure with low levels of N and O impurities. The films deposited with H_2 gas at ≤200 °C are faced centered cubic-phase Ni metal films with low C content; but at ≥220 °C, another phase of rhombohedral Ni_3C is formed and the C content increases. However, when H_2 plasma is used, the films are always in rhombohedral Ni3C phase for the entire temperature range.
DOI: 10.1021/acs.jpcc.6b01555
发表时间: 2016-10-06
影响因子: 3.7
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