Preparation, formation mechanism and photoelectric properties of well-aligned CuSbS2 nanowires

Preparation, formation mechanism and photoelectric properties of well-aligned CuSbS2 nanowires
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定向排列CuSbS2纳米线的制备、形成机制及光电性能

DOI:
10.1016/j.jallcom.2015.07.030
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发表时间:
2015-11
影响因子:
6.2
通讯作者:
Dai Yumei
Dai Yumei
中科院分区:
材料科学2区
文献类型:
--
作者:
Shi Liang;Li Yanan;Wu Chunyan;Dai Yumei

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采用溶剂热合成的方法制备了排列良好的cusbs2单晶纳米线阵列。制备的cusbs2纳米线均匀,生长方向垂直于(101)面。采用多孔阳极氧化铝作为形貌定向模板,对单晶cusbs2纳米线的形成起着重要的作用。由cusbs2纳米线制备的薄膜表现出明显的光电响应,表明其作为低成本太阳能吸收材料的潜在应用前景。提出了单晶cusbs2纳米线阵列的可能形成机制。采用x射线粉末衍射、扫描电镜、透射电镜、能量色散x射线光谱法和紫外可见分光光度法对制备的cusbs2纳米线的结构、形貌、组成和光吸收性能进行了表征。
Well-aligned CuSbS2single crystalline nanowires array has been prepared via a solvothermal synthetic route. The as-prepared CuSbS2nanowires are uniform with a growth direction perpendicular to the (101) planes. Porous anodic aluminum oxide was used as a morphology directing template and was found to play a significant role for the formation of single crystalline CuSbS2nanowires. Thin film prepared from CuSbS2nanowires displayed an obvious photoelectric response, suggesting its potential application as a low cost solar absorber material. A possible formation mechanism for the single crystalline CuSbS2nanowires array is proposed. The structure, morphology, composition and optical absorption properties of the as-prepared CuSbS2nanowires were characterized using X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectrometry and UV–Vis spectrophotometry.
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