Annealing effect on the bipolar resistive switching characteristics of a Ti/Si3N4/n-GaN MIS device

Annealing effect on the bipolar resistive switching characteristics of a Ti/Si3N4/n-GaN MIS device
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退火对 Ti/Si3N4/n-GaN MIS 器件双极阻变特性的影响

DOI:
10.1016/j.jallcom.2018.01.072
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发表时间:
2018-04
影响因子:
6.2
通讯作者:
Song Hang
Song Hang
中科院分区:
材料科学2区
文献类型:
--
作者:
Chen Yiren;Li Zhiming;Zhang Zhiwei;Hu Liqin;Jiang Hong;Miao Guoqing;Song Hang

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本文研究了退火对Ti/Si 3 N4/n-GaN金属-绝缘体-半导体(MIS)结构忆阻器双极阻变特性的影响。结果表明,退火后的Ti/Si_3N_4/n-GaN MIS器件的双极阻变特性的稳定性和重复性得到了很大的提高。导电力显微镜(CFM)和X射线光电子能谱(XPS)揭示了所涉及的机制。热退火证实了Si_3 N_4中的Ti是原位掺杂的,这是由于Si_3 N_4中的Ti在正偏压下通过电还原过程与N原子结合,有利于形成稳定的纳米Si丝。相反,在负偏压下,Si细丝通过与n-GaN侧附近的N原子复合而断裂。该器件易于与GaN基高电子迁移率晶体管(HEMT)集成,构成一管一阻(1 T1 R)的非易失性存储单元,有望拓展氮化物半导体在发光二极管、激光二极管、功率器件、光电探测器等领域的应用,并在数据存储领域发挥重要作用。
In this paper, the effect of annealing on the bipolar resistive switching characteristics of a Ti/Si3N4/n-GaN metal-insulator-semiconductor (MIS) structure memristor is demonstrated. The results show that the stability and repeatability of the bipolar resistive switching are greatly improved in annealed Ti/Si3N4/n-GaN MIS devices. The mechanism involved is revealed by both conductive force microscopy (CFM) and x-ray photoelectron spectroscopy (XPS). It is confirmed toin-situlocal Ti doping in Si3N4by thermal annealing and can be ascribed to the local Ti dopants in the Si3N4bonding the N atoms at positive bias by electro-reductive process that benefits to form stable nanoscale Si filaments. On the contrary, the Si filaments rupture by recombining with N atoms near the n-GaN side at negative bias. The proposed device is apt to integrate with a GaN-based high electron mobility transistor (HEMT) to structure a one-transistor-one-resistor (1T1R) nonvolatile memory cell, which is expected to develop the application of the nitride semiconductors in data storage in addition to the applications in light-emitting diodes, laser diodes, power devices, and photodetectors.
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