Effect of gamma irradiation on (K,Na,Li)(Ta,Nb)O3–CaZrO3 lead-free ferroelectric film grown on La0.67Ba0.33MnO3 and La0.67Ca0.33MnO3 conductive oxide electrode

Effect of gamma irradiation on (K,Na,Li)(Ta,Nb)O3–CaZrO3 lead-free ferroelectric film grown on La0.67Ba0.33MnO3 and La0.67Ca0.33MnO3 conductive oxide electrode
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γ辐照对La0.67Ba0.33MnO3和La0.67Ca0.33MnO3导电氧化物电极上生长的(K,Na,Li)(Ta,Nb)O3-CaZrO3无铅铁电薄膜的影响

DOI:
10.1016/j.jallcom.2019.152148
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发表时间:
2020-06
影响因子:
6.2
通讯作者:
Bao Jingfu
Bao Jingfu
中科院分区:
材料科学2区
文献类型:
--
作者:
Qin Feng;Sun Xiangyu;Gong Dongdong;Wang Yicheng;Chen Yu;Xu Liqiang;Chen Feng;Du Yijia;Bao Jingfu

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(K1-xNax)NbO 3(KNN)基无铅铁电材料具有较大的压电系数,被认为是替代传统铅基铁电材料的最有希望的材料。材料的耐辐照性对于在强辐照环境中的应用,特别是在耐辐照器件中的可能应用是重要的。本文以La0.67Ca0.33MnO3(LCMO)和La0.67Ba0.33MnO3(LBMO)导电氧化物为底电极,金属Pt为顶电极,在SrTiO 3(001)衬底上生长了0.95(K0.49Na0.49Li0.02)(Ta0.2Nb0.8)O3-0.05CaZrO3(KNN-LT-CZ)无铅薄膜。Pt/KNN-LT-CZ/LCMO和Pt/KNN-LT-CZ/LBMO薄膜在50 Mrad(Si)γ射线辐照前后的剩余极化衰减分别高达21%和26%。辐照后,后者的介电常数仅下降了10%,而前者的介电常数却下降了10%。在导电金属氧化物上生长的KNN-LT-CZ膜具有良好的耐辐照性,这最终将有利于在更坚韧的环境中应用的器件的未来设计优化。
(K1-xNax)NbO3(KNN)-based lead-free ferroelectric materials featured with the large piezoelectric coefficient, has long been considered as a very promising candidate to replace traditional lead-based ferroelectric materials. Irradiation resistance of materials is important for the application in strong irradiation environments, especially possible application in irradiation resistance devices. In this paper, 0.95(K0.49Na0.49Li0.02)(Ta0.2Nb0.8)O3-0.05CaZrO3(KNN-LT-CZ) lead-free thin films have been grown on SrTiO3(001) substrates with La0.67Ca0.33MnO3(LCMO) and La0.67Ba0.33MnO3(LBMO) conductive oxide as bottom electrodes and metallic Pt as top ones. As large as 21% and 26% remnant polarization decay are distinguished in Pt/KNN-LT-CZ/LCMO and Pt/KNN-LT-CZ/LBMO films respectively, before and after gamma ray irradiation of 50 Mrad(Si). The irradiation even induced exotic current behavior in the latter ones, while the former ones exhibit only 10% decrease of the dielectric constant. The KNN-LT-CZ film grown on conductive metal oxides is associated with favorable irradiation resistance which would eventually benefit future design optimization in devices applied in more tough environments.
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