Acquisition of a High-field FT NMR Spectrometer for Under- graduate Research and Instruction

购置高场 FT NMR 波谱仪用于本科生研究和教学

• 批准号: 8851627
• 负责人: James Duncan
• 金额: $ 6.27万
• 依托单位: Lewis and Clark College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1988
• 资助国家: 美国
• 起止时间: 1988-06-01 至 1990-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=8851627&HistoricalAwards=false
• 关键词: Acquisition; field; FT; NMR; Spectrometer

A High-Field Fourier Transform Nuclear Magnetic Resonance Spectrometer System including variable temperature, hard disk, and coprocessor accessories is being used to introduce new experiments in the Physical, Inorganic, Advanced Analytical, and Introductory Organic Chemistry Laboratory Courses. The scientific productivity of the undergraduate research program is being substantially increased. Examples of student research projects which are being made possible by this instrument included: (I) studies of the stereochemistry of augmented thermal and photochemical Cope rearrangements; (II) synthesis and studies of the regio- and stereochemistry of dealkoxycarbonylation reactions of thienyl substituted polyalkoxycarbonyl ethenes as possible polythienyl precursors; (III) synthesis and conformational studies of Schiff base coordination compounds as possible laser materials; and (IV) the synthesis of silicone compounds of theoretical interest. The grantee is matching the award from non-Federal sources.

高场傅里叶变换核磁共振波谱仪系统包括可变温度、硬盘和协处理器附件，用于在物理、无机、高级分析和有机化学入门实验室课程中介绍新的实验。本科生研究项目的科学生产率正在大幅提高。该仪器使学生研究项目成为可能的例子包括：(I)增强的热和光化学钴重排的立体化学研究；(Ii)作为可能的多亚硫基前体的噻吩基取代的聚烷氧基羰基乙烯的区域和立体化学的合成和研究；(Iii)席夫碱配位化合物的合成和构象研究，作为可能的激光材料；以及(Iv)合成具有理论意义的有机硅化合物。受赠人匹配来自非联邦来源的奖励。