Purchase of a High Resolution Mass Spectrometer

质谱技术，例如电子轰击（EI）、快速质谱（Fast Spectrometry）和质谱分析（MS）。 原子轰击（FAB）和化学电离（CI）被使用 来探测内部结构的细节， 一系列有机、生物有机和 有机金属化合物 使用能够 执行这些最先进的技术是必不可少的 在若干领域进行前沿研究， 化学. 佛罗里达大学化学系将 利用化学仪表计划的这一奖项， 帮我弄个质谱仪 化学领域 此次收购将加强的研究包括 以下内容： 1)过渡金属重排的卡宾配合物 σ络合物和应变联烯：游离和络合， 过渡金属 2)氟取代基的动力学和立体化学效应 在热均裂和周环反应中 3)杂环阳离子，苯并三唑化学，治疗学 以及多价碘衍生物 4)烯反应和二碘化钐的合成研究 介导的反应 5)电化学和质谱法在生物化学研究中的应用 代谢氧化还原反应机制 6)金属配合物与单克隆抗体的气相反应 针对金属络合物的抗体。

Mass spectral techniques such as Electron Impact (EI), Fast Atom Bombardment (FAB), and Chemical Ionization (CI) are used to probe intimate structural details and to obtain molecular compositions of a vast array of organic, bioorganic and organometallic compounds. Access to instrumentation capable of carrying out these state-of-the-art techniques is essential for the prosecution of frontier research in several fields of chemistry. The Department of Chemistry at the University of Florida will use this award from the Chemical Instrumentation Program to help acquire a mass spectrometer. The areas of chemical research that will be enhanced by the acquisition include the following: 1) Carbene complexes from rearrangement of transition metal sigma complexes and strained allenes: free and complexed to transition metals 2) Kinetic and stereochemical effects of fluorine substituents in thermal homolytic and pericyclic reactions 3) Heterocyclic cations, benzotriazole chemistry, thermolysis of organics, and polyvalent iodine derivatives 4) Synthetic studies of the ene reaction and samarium diiodide mediated reactions 5) Electrochemistry and mass spectrometry in the study of metabolic redox reactions mechanisms 6) Gas-phase reactions of metal complexes and monoclonal antibodies elicited against metal complexes.