Structures and Reactions of New Main-Group Organometallic Compounds

在本项目（“新主群的结构和反应 有机化合物”）由有机动力学资助 化学系教授赫尔曼G.里奇 宾夕法尼亚州立大学化学系 将研究新化合物的结构和反应， 主族元素的有机金属物种。 这项研究将 还涉及制备新的有机金属化合物和产生 一种新的活性更高的有机镁化合物。 该项目将涉及准备和研究 由有机镁化合物通过加成形成的物质 冠醚或简单盐，如碱金属醇盐 和四烷基卤化铵。 这些新物种， 包括配位有机镁阳离子、螺纹 有机镁-冠醚和各种有机镁盐 阴离子，比传统的活性高得多 有机镁化合物，并与一些基板提供 不同的产品。 其范围和机制 将研究与酮的反应和其它反应。 类似的研究有机锌酸盐阴离子形成的， 也可以使用有机锌化合物和盐。

In this project ("Structures and Reactions of New Main-Group Organometallic Compounds") funded by the Organic Dynamics Program of the Chemistry Division, Professor Herman G. Richey in the Chemistry Department at Pennsylvania State University will investigate the structures and reactions of new organometallic species of main-group elements. The study will also involve preparation of new organometallics and generating a new species of more reactive organomagnesium compounds. This project will be concerned with the preparation and study of species formed from organomagnesium compounds by additions of crown ethers or simple salts, such as alkali metal alkoxides and tetraalkylammonium halides. These new species, which include coordinated organomagnesium cations, threaded organomagnesium-crown ethers, and various organomagnesiate anions, are considerably more reactive than conventional organomagnesium compounds, and with some substrates afford different products. The scope and mechanisms of their reactions with ketones and other reactions will be studied. Similar investigations of organozincate anions formed from organozinc compounds and salts will also be performed.