Mass Spectrometry for Augmenting Organic and Inorganic Synthesis

堪萨斯州立大学化学系将利用化学研究仪器项目的这笔资金来帮助获得质谱仪系统。此次收购将加强的化学研究领域包括：1)活化环丁烯的二醛化学，2)天然产物和生物医学分子的不对称合成，3)纳米级金属氧化物颗粒表面有机分子的碎片化，4)SMAD催化剂的性能，单硫化碳（CS）的有机前体，5)对苯基二酰亚胺桥接二聚体和聚合物。一类新的共轭无机体系，以及6)向碳氢铁磁体方向发展：聚芳基甲基。质谱法是一种用于探测内部结构细节和获得大量有机、生物有机和有机金属分子的分子组成的技术。当与高效液相色谱仪相结合时，所得到的系统为化学家提供了分离和表征化合物的最强大的工具之一。在化学的许多领域进行前沿研究时，获得质谱仪是必不可少的。

The Department of Chemistry at Kansas State University will use this award from the Chemistry Research Instrumentation Program to help acquire a mass spectrometer system. The areas of chemical research that will enhance by the acquisition include the following: 1) Diels - Alder Chemistry of Activated Cyclobutenes, 2) Asymmetric Synthesis of Natural Products and Molecules of Biomedical Interest, 3) Organic Molecule Fragmentations on the Surfaces of Nano-scale Metal Oxide Particles, 4) Performance of SMAD Catalysts Organic Precursors to Carbon Monosulfide (CS), 5) p-Phenylenediimido-Bridged Dimers and Polymers. A New Class of Conjugated Inorganic Systems, and 6) Toward a Hydrocarbon Ferromagnet: Polyarylmethyls. Mass spectrometry is a technique used to probe intimate structural details and to obtain the molecular compositions of a vast array of organic, bioorganic and organometallic molecules. When combined with a high performance liquid chromatograph, the resulting system affords the chemist one of the most powerful tools available for the separation and characterization of compounds. The acquisition of a mass spectrometer is essential for the prosecution of frontier research in many fields of chemistry.