Synthetic Strategies for the Achievement of Directed and Controlled Synthesis of Solid State Metal Oxides and Sulfides

实现固态金属氧化物和硫化物定向可控合成的合成策略

• 批准号: 9224279
• 负责人: Omar Yaghi
• 金额: $ 3.2万
• 依托单位: Arizona State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-01-15 至 1994-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9224279&HistoricalAwards=false
• 关键词: Synthetic; Strategies; Achievement; Directed; Controlled

This award is made as the starter grant increment of Dr. Omar Yaghi's Postdoctoral Fellowship in Chemistry Award in support of his research at Arizona State University. The theme of the research is the development of synthetic strategies for the rational synthesis of solid state metal oxides and sulfides. Part of the work entails aggregating clusters using heteroatoms or organic molecules capable of binding selectively to the face or edge of a cluster. The remainder of the work involves hydrothermal synthesis of microporous sulfides using molecular metal sulfides known to be stable to hydrolysis. %%% The development of new methods for the preparation of solid state materials can lead to the discovery of compounds which may have novel electrical and mechanical properties. These substances may have commercial significance in the chemical industry.

该奖项是作为奥马尔博士的启动补助金增量 Yaghi的博士后研究金化学奖，以支持 他在亚利桑那州立大学的研究成果。 的主题 研究是发展综合战略， 固态金属氧化物和硫化物的合理合成。 部分工作需要使用杂原子聚集簇 或者能够选择性地结合到面部的有机分子 或集群的边缘。 剩下的工作包括 分子水热法合成微孔硫化物 已知对水解稳定的金属硫化物。 %%% 固体制备新方法的发展 国家材料可以导致化合物的发现， 可以具有新颖的电性能和机械性能。 这些 化学品中可能具有商业意义的物质 行业