Synthetic, Structural and Mechanistic Studies of Alkyl, Hydride and Other Derivatives of the S- and P- Block Metals
S 和 P 嵌段金属的烷基、氢化物和其他衍生物的合成、结构和机理研究
基本信息
- 批准号:9300398
- 负责人:
- 金额:$ 26.45万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Continuing Grant
- 财政年份:1993
- 资助国家:美国
- 起止时间:1993-05-15 至 1997-04-30
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award in the Inorganic, Bioinorganic, and Organometallic Program provides continued support for the work of Dr. Gerard F. R. Parkin of the Chemistry Department, Columbia University, on main group metals. Monomeric complexes containing poly(pyrazolyl)hydroboratate ligands will be prepared, including alkyl and hydride derivatives, carbonyl derivatives, subvalent derivatives, and terminal oxo, sulfido, and imido complexes. Multiple bonding with heavy main group compounds will receive particular attention. Attempts will be made to isolate structurally homologous complexes so that comparisons can be made between the reactions of particular metals. Alkyl derivatives of members of Group 2 beyond beryllium will be characterized. Synthesis of anionic copper(I) hydrides will be be attempted, as well as that of new CO complexes of silver and gold. The reactivity of Zn, Cd, and Hg species will be compared to that of Group 2. %%% Main group metals are used as reagents in organic synthesis and are important components of ceramic materials, semiconductors, and superconductors. This work would provide fundamental information about the behavior of these metals, particularly the heavy members whose chemistry is less well known, and whose usefulness in materials applications has not been fully exploited.
该奖项授予无机物、生物无机和有机金属项目,为哥伦比亚大学化学系Gerard F.R.Parkin博士在主要族金属方面的工作提供持续支持。将制备含多(吡唑基)氢硼酸盐配体的单体络合物,包括烷基和氢化物、羰基、亚价衍生物,以及末端氧、硫和亚胺络合物。与重主族化合物的多重成键将受到特别关注。将尝试分离结构上同源的络合物,以便可以在特定金属的反应之间进行比较。将表征除铍以外的第2族成员的烷基衍生物。将尝试合成阴离子铜(I)氢化物,以及新的银和金的CO络合物。锌、镉和汞的反应性将与族2的反应性进行比较。主族金属在有机合成中用作试剂,是陶瓷材料、半导体、和超导体。这项工作将提供有关这些金属的行为的基本信息,特别是那些化学成分不太为人所知,其在材料应用中的有用性尚未被充分开发的重金属元素。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
数据更新时间:{{ journalArticles.updateTime }}
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
数据更新时间:{{ journalArticles.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ monograph.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ sciAawards.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ conferencePapers.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ patent.updateTime }}
Gerard Parkin其他文献
The synthesis and molecular structures of 2,5-diarylpyrroles, $$[{\text{pyr}}^{{\text{Ar}}_{\text{2}} } ]$$ H (Ar = Ph, 2,4-Xyl)
- DOI:
10.1023/a:1020239919672 - 发表时间:
2002-07-01 - 期刊:
- 影响因子:0.600
- 作者:
Joseph M. Tanski;Gerard Parkin - 通讯作者:
Gerard Parkin
Reactivity of <math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si1.gif" overflow="scroll" class="math"><mrow><mo stretchy="false">[</mo><msup><mrow><mtext>Tism</mtext></mrow><mrow><msup><mrow><mtext>Pr</mtext></mrow><mtext>i</mtext></msup><mtext>Benz</mtext></mrow></msup><mo stretchy="false">]</mo></mrow></math>MgMe towards secondary amines and terminal alkynes: Catalytic dehydrocoupling with hydrosilanes to afford Si–N and Si–C bonds
- DOI:
10.1016/j.ica.2019.03.015 - 发表时间:
2019-08-01 - 期刊:
- 影响因子:
- 作者:
Michael Rauch;Renee C. Roberts;Gerard Parkin - 通讯作者:
Gerard Parkin
<em>Ansa</em>-titanocene pyrrolyl complexes: The synthesis and structural characterization of [Me<sub>2</sub>Si(C<sub>5</sub>Me<sub>4</sub>)<sub>2</sub>]Ti(NC<sub>4</sub>H<sub>4</sub>)X (X = H, Me, Cl and NC<sub>4</sub>H<sub>4</sub>) and [Me<sub>2</sub>Si(C<sub>5</sub>Me<sub>4</sub>)(C<sub>5</sub>Me<sub>3</sub>CH<sub>2</sub>)]Ti(NC<sub>4</sub>H<sub>4</sub>)
- DOI:
10.1016/j.poly.2005.04.005 - 发表时间:
2005-08-04 - 期刊:
- 影响因子:
- 作者:
Hyosun Lee;Jeffrey B. Bonanno;Brian M. Bridgewater;David G. Churchill;Gerard Parkin - 通讯作者:
Gerard Parkin
Synthesis of bis(2-pyridylthio)methyl zinc hydride and catalytic hydrosilylation and hydroboration of COsub2/sub
双(2-吡啶硫基)甲基锌氢化物的合成以及二氧化碳的催化氢化硅烷化和氢化硼化
- DOI:
10.1039/d1cc06963b - 发表时间:
2022-01-01 - 期刊:
- 影响因子:4.200
- 作者:
Daniel G. Shlian;Erika Amemiya;Gerard Parkin - 通讯作者:
Gerard Parkin
The photochemical reactivity of bis(tert-butylcyclopentadienyl)molybdenum dihydride: synthesis and structure of dinuclear trans-[(CpBu t)Mo(μ-σ,η 5-C5H3But)H]2
- DOI:
10.1023/a:1023889329072 - 发表时间:
2003-04-01 - 期刊:
- 影响因子:0.600
- 作者:
David G. Churchill;Jun Ho Shin;Gerard Parkin - 通讯作者:
Gerard Parkin
Gerard Parkin的其他文献
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
{{ truncateString('Gerard Parkin', 18)}}的其他基金
Main Group Metal Compounds with Terminal Hydride and Hydroxide Ligands: Synthesis and Applications
具有末端氢化物和氢氧化物配体的主族金属化合物:合成与应用
- 批准号:
1955648 - 财政年份:2020
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant
Metallacarbatrane, Hydride, Fluoride, and Metal-Metal Bonded Compounds of the Main Group Elements: Synthesis and Applications
金属碳氢化合物、氢化物、氟化物和主族元素的金属-金属键化合物:合成与应用
- 批准号:
1465095 - 财政年份:2015
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant
Main Group Element Complexes Supported by Multidentate Ligands: Alkyl, Hydride and Subvalent Compounds and their Applications to Catalysis
多齿配体支持的主族元素配合物:烷基、氢化物和次价化合物及其在催化中的应用
- 批准号:
1058987 - 财政年份:2011
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant
Individual: NSF Presidential Award for Excellence in Science, Mathematics and Engineering Mentoring (Gerard Parkin)
个人:美国国家科学基金会科学、数学和工程指导卓越总统奖(杰拉德·帕金)
- 批准号:
0933971 - 财政年份:2011
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant
Synthetic, Structural and Mechanistic Studies of Main Group Element Complexes: Atom Transfer Reactions and Subvalent Compounds.
主族元素配合物的合成、结构和机理研究:原子转移反应和亚价化合物。
- 批准号:
0749674 - 财政年份:2008
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
MRI: Acquisition of an X-Ray Diffractometer at Columbia University For Use in Research and Education
MRI:在哥伦比亚大学购买 X 射线衍射仪用于研究和教育
- 批准号:
0619638 - 财政年份:2006
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant
Synthetic, Structural and Mechanistic Studies of s- and p-Block Metal Complexes with Multiply Bonded and Other Reactive Functionalities
具有多重键合和其他反应性官能团的 s 和 p 区金属配合物的合成、结构和机理研究
- 批准号:
0350498 - 财政年份:2004
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Upgrade of a 500 MHz NMR Spectrometer
500 MHz NMR 波谱仪的升级
- 批准号:
0130308 - 财政年份:2002
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant
Synthetic, Structural, and Mechanistic Studies of s- and p-Block Element Complexes with Reactive Functionalities
具有反应性功能的 s 和 p 块元素配合物的合成、结构和机理研究
- 批准号:
9987432 - 财政年份:2000
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Synthetic, Structural, and Mechanistic Studies of Monomeric Alkyl, Hydride, Sub-Valent, and Multiply Bonded Derivatives of the s-and p-Block Elements
s 和 p 块元素的单体烷基、氢化物、亚价和多重键衍生物的合成、结构和机理研究
- 批准号:
9610497 - 财政年份:1997
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
相似国自然基金
Understanding structural evolution of galaxies with machine learning
- 批准号:n/a
- 批准年份:2022
- 资助金额:10.0 万元
- 项目类别:省市级项目
相似海外基金
Stereospecific arylation of organolithiums: synthetic, mechanistic and structural investigation
有机锂的立体定向芳基化:合成、机理和结构研究
- 批准号:
EP/F069103/1 - 财政年份:2009
- 资助金额:
$ 26.45万 - 项目类别:
Research Grant
Stereospecific arylation of organolithiums: synthetic, mechanistic and structural investigation
有机锂的立体定向芳基化:合成、机理和结构研究
- 批准号:
EP/G000816/1 - 财政年份:2008
- 资助金额:
$ 26.45万 - 项目类别:
Research Grant
Synthetic, Structural and Mechanistic Studies of Main Group Element Complexes: Atom Transfer Reactions and Subvalent Compounds.
主族元素配合物的合成、结构和机理研究:原子转移反应和亚价化合物。
- 批准号:
0749674 - 财政年份:2008
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Synthetic, Structural and Mechanistic Studies of s- and p-Block Metal Complexes with Multiply Bonded and Other Reactive Functionalities
具有多重键合和其他反应性官能团的 s 和 p 区金属配合物的合成、结构和机理研究
- 批准号:
0350498 - 财政年份:2004
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Cyclophane Carbene Complexes as Catalysts: An Integrated Synthetic, Structural, and Mechanistic Approach
环芳卡宾配合物作为催化剂:综合合成、结构和机理方法
- 批准号:
DP0344334 - 财政年份:2003
- 资助金额:
$ 26.45万 - 项目类别:
Discovery Projects
Cyclophane Carbene Complexes as Catalysts: An Integrated Synthetic, Structural, and Mechanistic Approach
环芳卡宾配合物作为催化剂:综合合成、结构和机理方法
- 批准号:
ARC : DP0344334 - 财政年份:2003
- 资助金额:
$ 26.45万 - 项目类别:
Discovery Projects
Synthetic, Structural, and Mechanistic Studies of s- and p-Block Element Complexes with Reactive Functionalities
具有反应性功能的 s 和 p 块元素配合物的合成、结构和机理研究
- 批准号:
9987432 - 财政年份:2000
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Synthetic, Structural, and Mechanistic Studies of Monomeric Alkyl, Hydride, Sub-Valent, and Multiply Bonded Derivatives of the s-and p-Block Elements
s 和 p 块元素的单体烷基、氢化物、亚价和多重键衍生物的合成、结构和机理研究
- 批准号:
9610497 - 财政年份:1997
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Synthetic, Structural and Mechanistic Metallacyclobutene Chemistry
金属环丁烯的合成、结构和机理化学
- 批准号:
9520213 - 财政年份:1996
- 资助金额:
$ 26.45万 - 项目类别:
Continuing Grant
Synthetic, Structural and Mechanistic Investigations of New Derivatives of the Early Transition Metals Having Reactive Ligands
具有活性配体的早期过渡金属新衍生物的合成、结构和机理研究
- 批准号:
9506413 - 财政年份:1995
- 资助金额:
$ 26.45万 - 项目类别:
Standard Grant