Stereospecific arylation of organolithiums: synthetic, mechanistic and structural investigation

有机锂的立体定向芳基化：合成、机理和结构研究

• 批准号: EP/G000816/1
• 负责人: Andrew Edward Henry Wheatley
• 金额: $ 17.54万
• 依托单位: University of Cambridge
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2008
• 资助国家: 英国
• 起止时间: 2008 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FG000816%2F1
• 关键词: Stereospecific; arylation; organolithiums; synthetic; mechanistic

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

目前，所有资助研究的摘要都不能在GTR中找到。这通常是因为在提交提案时并不需要摘要，但可能是因为它包含了个人详细信息等敏感信息。

项目成果

On the control of secondary carbanion structure utilising ligand effects during directed metallation.

• DOI: 10.3762/bjoc.8.5
• 发表时间: 2012
• 期刊: Beilstein journal of organic chemistry
• 影响因子: 2.7
• 作者: Wheatley AE;Clayden J;Hillier IH;Campbell Smith A;Vincent MA;Taylor LJ;Haywood J
• 通讯作者: Haywood J

Ligand effects in the formation of tertiary carbanions from substituted tertiary aromatic amides.

从取代的叔芳族酰胺形成叔碳负离子的配体效应。

• DOI: 10.1002/chem.201100240
• 发表时间: 2011
• 期刊: Chemistry (Weinheim an der Bergstrasse, Germany)
• 作者: Smith AC

Lithiated tertiary carbanions display variable coordination modes: evidence from DFT and NMR studies.

锂化叔碳负离子显示出不同的配位模式：来自 DFT 和 NMR 研究的证据。

• DOI: 10.1002/chem.201200734
• 发表时间: 2012
• 期刊: Chemistry (Weinheim an der Bergstrasse, Germany)
• 作者: Vincent MA