New Organic Molecules with Unusual Structures and Properties

具有不寻常结构和性质的新型有机分子

• 批准号: 9422977
• 负责人: Lawrence Scott
• 金额: $ 42.6万
• 依托单位: Boston College
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1995
• 资助国家: 美国
• 起止时间: 1995-01-15 至 1998-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9422977&HistoricalAwards=false
• 关键词: New; Organic; Molecules; Unusual; Structures

The focus of this research is the synthesis of corannulene homologs containing 16, 21 and 26 rings. These derivatives will be used to form upramolecular complexes with C-60 and other fullerenes. Other targets include barrelyne and 60-carbon molecules that could provide key intermediates for the preparation of endohedral complexes of C-60. New understanding in the area contains the potential for the rational development of new advanced materials. With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Lawrence T. Scott of the Department of Chemistry at Boston College. Professor Scott will focus his wok on constructing novel organic molecules. The target compounds are characterized by by highly condensed, convex networks of trigonal carbons that map onto the polyatomic framework of the fullerenes. New understanding in this area could lead to the rational development of advanced materials having potential importance in the emerging realm of nanotechnology.

本研究的重点是合成含16、21和26个环的棒轮烯同系物。这些衍生物将用于与C-60和其他富勒烯形成超分子络合物。其他目标包括Barrelyne和60-碳分子，它们可以为制备C-60的内面体络合物提供关键的中间体。对这一领域的新认识蕴含着合理开发新的先进材料的潜力。有了这一续期奖，合成有机计划将支持波士顿学院化学系的劳伦斯·T·斯科特博士的研究。斯科特教授将把他的工作重点放在构建新型有机分子上。目标化合物的特征是高度浓缩的三角碳的凸起网络，这些网络映射到富勒烯的多原子框架上。对这一领域的新认识可能导致先进材料的合理发展，这些材料在新兴的纳米技术领域具有潜在的重要性。