Mechanisms of Activation of Organic Molecules by Neutral Metals in the Gas Phase

气相中性金属活化有机分子的机理

• 批准号: 9531244
• 负责人: Douglas Grotjahn
• 金额: $ 15.66万
• 依托单位: Arizona State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1996
• 资助国家: 美国
• 起止时间: 1996-04-15 至 1998-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9531244&HistoricalAwards=false
• 关键词: Mechanisms; Activation; Organic; Molecules; Neutral

The focus of this research project is to determine the reaction dynamics of gas phase reactions between neutral metal atoms and small organic substrates. This collaborative effort will involve synthesis of labelled substrates such as carbon dioxide, organic halides and alkanes. Analysis of the reaction dynamics will be done using mass spectrometry and rotational spectroscopy. With this award, the Organic Dynamics Program is supporting fundamental studies in the area of neutral metal reaction dynamics. Professors Grotjahn and Ziurys will focus on the reactions between small organic molecules and neutral metal atoms. These results will help future investigators determine details regarding energy barriers and ligand effects.

该研究项目的重点是确定中性金属原子与小型有机底物之间气相反应的反应动力学。这项合作将涉及标记底物的合成，例如二氧化碳、有机卤化物和烷烃。将使用质谱法和旋转光谱法对反应动力学进行分析。 有机动力学计划通过该奖项支持中性金属反应动力学领域的基础研究。 Grotjahn 和 Ziurys 教授将重点研究有机小分子和中性金属原子之间的反应。这些结果将帮助未来的研究人员确定有关能量势垒和配体效应的细节。