Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry

有机和无机化学中二硼烷和四卤二硼烷的路易斯碱活化

• 批准号: 396769488
• 负责人: Professor Dr. Holger Braunschweig
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2018
• 资助国家: 德国
• 起止时间: 2017-12-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/396769488?language=en
• 关键词: Lewis; Base; Activation; Di; Tetrahalodiboranes

Over the last decade, the element boron has moved to the forefront of synthetic organic chemistry and the industries that depend on it, including the pharmaceutical, agrochemical, and fine chemical industries. This progress would have been impossible without one key family of inorganic molecules: diboranes. This proposal takes aim at two less well-studied examples of diboranes: di- and tetrahalodiboranes. The chemistry of these compounds, despite their long history, is still poorly understood due to their inherent reactivity. However, the potential benefits of further work with these reactive and unpredictable complexes is vast, both to inorganic and organic chemistry.

在过去的十年中，硼元素已经进入了合成有机化学和依赖于它的行业的最前沿，包括制药，农用化学品和精细化工行业。如果没有一个关键的无机分子家族：乙硼烷，这一进展是不可能的。该提议针对的是二硼烷的两个研究较少的例子：二卤代二硼烷和四卤代二硼烷。这些化合物的化学，尽管其历史悠久，由于其固有的反应性，仍然知之甚少。然而，进一步研究这些反应性和不可预测的复合物的潜在好处是巨大的，无论是无机化学还是有机化学。