CAREER: Catalytic Reactions Involving C1 Feedstocks: Development of High Activity Catalysts for the Copolymerization of Carbon Dioxide and Epoxides
CAREER: Catalytic Reactions Involving C1 Feedstocks: Development of High Activity Catalysts for the Copolymerization of Carbon Dioxide and Epoxides
批准号:
9875261
负责人:
Geoffrey Coates
金额:
$32.8万
依托单位:
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1999
资助国家:
美国
项目状态:
已结题
起止时间:
1999-02-15 至 2004-01-31
中文摘要
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英文摘要
This CAREER award in the Inorganic, Bioinorganic, and Organometallic Chemistry Program supports research and education on polymer synthesis by Dr. Geoffrey W. Coates in the Chemistry Department, Cornell University. The goal of the research is to develop new catalysts for the controlled copolymerization of carbon dioxide and epoxides. Transition metal complexes, specifically zinc diimines and chiral oxazolines, will be used as initiators for polymers that have heterocyclic groups in the main chain. By modification of these groups, polymers that are biodegradable are expected to result. The mechanism of the reaction will be investigated, as will potential synthetic applications. Polymer chemistry will be the basis of outreach programs to K-12 students, redesign of a portion of the undergraduate organic chemistry laboratory, and industrial interactions for graduate students. The Cornell Center for Materials Research will be the focus for many of these activities.
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DMREF: Collaborative Research: Next-Generation Nanostructured Polymer Electrolytes by Molecular Design
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批准号:1334410
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项目类别:Standard Grant
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资助金额:$40.0万
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财政年份:2013
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负责人:Geoffrey Coates
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依托单位:
Bimetallic Catalysts for the Synthesis of Environmentally Benign Polymers
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批准号:1112278
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项目类别:Standard Grant
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资助金额:$51.1万
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财政年份:2011
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负责人:Geoffrey Coates
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依托单位:
Development of New Catalysts for the Synthesis of Biodegradable Polymers
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批准号:0809778
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项目类别:Continuing Grant
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资助金额:$49.1万
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财政年份:2008
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负责人:Geoffrey Coates
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依托单位:
FRG: GOALI: Collaborative Research: The Role of Polymer Molecular Architecture in Controlling Morphology in Quiescent and Flow-Induced Crystallization
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批准号:0706578
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项目类别:Continuing Grant
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资助金额:$32.0万
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财政年份:2007
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负责人:Geoffrey Coates
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依托单位:
NSF Workshop: Chemistry and Sustainability
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批准号:0602303
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项目类别:Standard Grant
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资助金额:$0.0万
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财政年份:2005
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负责人:Geoffrey Coates
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依托单位:
IMR: Acquisition of a MALDI-TOF Mass Spectrometer for Materials Research and Student Education
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批准号:0414741
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项目类别:Standard Grant
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资助金额:$13.92万
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财政年份:2004
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负责人:Geoffrey Coates
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依托单位:
Purchase of a 400 MHz NMR Spectrometer for Research and Teaching
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批准号:0320649
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项目类别:Standard Grant
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资助金额:$36.25万
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财政年份:2003
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负责人:Geoffrey Coates
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依托单位:
Development of Metal-Based Catalysts for the Synthesis of Polymers with Reduced Environmental Impact
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批准号:0243605
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项目类别:Continuing Grant
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资助金额:$51.5万
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财政年份:2003
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负责人:Geoffrey Coates
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依托单位:
Synthesis and Applications of Enantiomerically Pure Helicates
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批准号:9729214
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项目类别:Standard Grant
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资助金额:$4.0万
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财政年份:1997
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负责人:Geoffrey Coates
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依托单位:
Postdoctoral Research Fellowships in Chemistry
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批准号:9504678
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项目类别:Fellowship Award
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资助金额:$8.0万
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财政年份:1995
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负责人:Geoffrey Coates
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依托单位:
海外基金