Molecular Level Effects for Simple Electrode Reactions at Well Defined Polarizable Electrodes

明确的可极化电极上简单电极反应的分子水平效应

• 批准号: 0133758
• 负责人: W. Ronald Fawcett
• 金额: $ 42.16万
• 依托单位: University of California-Davis
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2002
• 资助国家: 美国
• 起止时间: 2002-02-01 至 2005-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0133758&HistoricalAwards=false
• 关键词: Molecular; Level; Effects; Simple; Electrode

Professor Ronald Fawcett of the University of California Davis is supported by the Analytical and Surface Chemistry Program to characterize the electrical double layer at single crystal gold microelectrode surfaces. Both novel experiments and theoretical studies will be performed. Aqueous and nonaqueous solvents will be investigated. Kinetic experiments will also be conducted at single crystal electrodes modified by a self-assembled monolayer. Monte Carlo calculations will be carried out to determine ion/electrode correlation functions in the diffuse boundary layer. This fundamental work underlies the understanding of electrochemical capacitors, synthesis, sensors, corrosion and the preparation of new materials.

加州大学戴维斯分校的Ronald Fawcett教授在分析和表面化学项目的支持下，对单晶金微电极表面的双电层进行了表征。将进行新颖的实验和理论研究。将研究水溶剂和非水溶剂。动力学实验也将在由自组装单层修饰的单晶电极上进行。蒙特卡罗计算将用于确定扩散边界层中的离子/电极相关函数。这项基础性工作奠定了对电化学电容器、合成、传感器、腐蚀和新材料制备的理解。