MRI: Acquisition and Construction of a Combined X-Band/Q-Band CW EPR/ENDOR Spectrometer

MRI:X 波段/Q 波段组合 CW EPR/ENDOR 光谱仪的采集和构建

基本信息

  • 批准号:
    0216277
  • 负责人:
  • 金额:
    $ 30.67万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Continuing Grant
  • 财政年份:
    2002
  • 资助国家:
    美国
  • 起止时间:
    2002-08-15 至 2005-07-31
  • 项目状态:
    已结题

项目摘要

With support from the Major Research Instrumentation (MRI) Program, Martin Kirk and colleagues at the University of New Mexico will acquire a combined X-band/Q-band CW EPR/ENDOR spectrometer. Projects that will exploit this instrument include a) studies of molybdoenzymes and relevant model complexes; b) research on thermally induced charge transfer materials; c) the use of cobalt as a spectroscopic probe of zinc sites in metalloproteins; d) spectroscopic studies of high symmetry cobalt coordination compounds; and e) biophysical studies of photosynthetic water oxidation and iron regulation. An electron paramagnetic resonance (EPR) spectrometer is an instrument used to obtain information about the molecular and electronic structure of molecules. It may also be used to obtain information about the lifetimes of free radicals which are often essential for the initiation of tumor growth and/or a variety of chemical reactions. These studies will have an impact in a number of areas, in particular biological chemistry.
在主要研究仪器(MRI)计划的支持下,新墨西哥州大学的Martin Kirk和同事将获得一个组合的X波段/Q波段CW EPR/ENDOR光谱仪。 将利用这一仪器的项目包括:a)对生物酶和相关模型复合物的研究; B)对热诱导电荷转移材料的研究; c)将钴用作金属蛋白中锌位点的光谱探针; d)对高对称性钴配位化合物的光谱研究;以及e)对光合作用水氧化和铁调节的生物物理研究。电子顺磁共振(EPR)光谱仪是一种用于获得分子和分子电子结构信息的仪器。它还可以用来获得有关自由基的寿命的信息,这些自由基通常是肿瘤生长和/或各种化学反应的起始所必需的。 这些研究将在一些领域产生影响,特别是生物化学。

项目成果

期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)

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Martin Kirk其他文献

Chalcogenidobis(ene-1, 2-dithiolate)molybdenum(IV) complexes : Probing Mo=E and ene-1, 2-dithiolato substituent effects on geometric and electronic structure
硫族双(烯-1, 2-二硫醇)钼(IV)配合物:探讨Mo=E和烯-1, 2-二硫醇取代基对几何和电子结构的影响
  • DOI:
  • 发表时间:
    2011
  • 期刊:
  • 影响因子:
    4
  • 作者:
    Hideki Sugimoto;Hiroyuki Miyake;Koichiro Suyama;Tomoya Kobayashi;Hiroyuki Miyake;Shinobu Itoh;Regina;Mtei;Martin Kirk
  • 通讯作者:
    Martin Kirk
Dioxo-Molybdenum(VI) Complexes with Ene-1, 2-dithiolate Ligand : Synthesis, Spectroscopy, and Oxygen Atom Transfer Reactivity
二氧代钼 (VI) 与 Ene-1, 2-二硫醇盐配体的配合物:合成、光谱学和氧原子转移反应性
  • DOI:
  • 发表时间:
    2009
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Hideki Sugimoto;Susumu Tatemoto;Koichiro Suyama;Hiroyuki Miyake;Shinobu Itoh;Chao Dong;Jin Yang;Martin Kirk
  • 通讯作者:
    Martin Kirk
X/Open Distributed Systems Management Program overview

Martin Kirk的其他文献

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{{ truncateString('Martin Kirk', 18)}}的其他基金

Spectroscopic and Electronic Structure Studies of Molecular Electron Transport and Excited State Processes
分子电子传输和激发态过程的光谱和电子结构研究
  • 批准号:
    1900237
  • 财政年份:
    2019
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
MRI: Acquisition of a Magnetic Property Measurement System (MPMS) To Support Research and Education in the State of New Mexico
MRI:采购磁特性测量系统 (MPMS) 以支持新墨西哥州的研究和教育
  • 批准号:
    1828744
  • 财政年份:
    2018
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
Donor-Acceptor Interactions and Their Relationship to Molecular Electronics and Excited State Processes.
供体-受体相互作用及其与分子电子和激发态过程的关系。
  • 批准号:
    1565930
  • 财政年份:
    2016
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
DONOR-ACCEPTOR INTERACTIONS, LONG-RANGE ELECTRON CORRELATION, AND DYNAMIC SPIN MANIPULATION: RELATIONSHIP TO MOLECULAR ELECTRONICS
供体-受体相互作用、长程电子相关性和动态自旋操纵:与分子电子学的关系
  • 批准号:
    1301142
  • 财政年份:
    2013
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
Acquisition of a Low-Field NMR Spectrometer for Research and Teaching
购置低场核磁共振波谱仪用于研究和教学
  • 批准号:
    0946690
  • 财政年份:
    2010
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
NANOSCALE ELECTRON CORRELATION AND FERROMAGNETIC EXCHANGE IN DONOR-ACCEPTOR BIRADICAL SYSTEMS: RELATIONSHIP TO MOLECULAR ELECTRONICS
供体-受体双自由基系统中的纳米级电子相关性和铁磁交换:与分子电子学的关系
  • 批准号:
    1012928
  • 财政年份:
    2010
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Continuing Grant
Upgrade of a 300 MHz NMR Spectrometer for Research and Teaching
升级 300 MHz NMR 波谱仪用于研究和教学
  • 批准号:
    0840523
  • 财政年份:
    2009
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
Electronic Structure Studies of Magnetic Donor-Acceptor Biradical Systems Related to Molecular Electronics
与分子电子学相关的磁性供体-受体双自由基系统的电子结构研究
  • 批准号:
    0616190
  • 财政年份:
    2006
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Continuing Grant
Electronic Structure Studies of Molybdenum Oxotransferases
钼氧化转移酶的电子结构研究
  • 批准号:
    9316557
  • 财政年份:
    1993
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Standard Grant
Postdoctoral Research Fellowships in Chemistry
化学博士后研究奖学金
  • 批准号:
    9002628
  • 财政年份:
    1990
  • 资助金额:
    $ 30.67万
  • 项目类别:
    Fellowship Award

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