Exploratory Synthesis of Novel Classes of Inorganic Solids of Electronic, Magnetic, and Catalytic Importance

具有电子、磁性和催化重要性的新型无机固体的探索性合成

• 批准号: 0322905
• 负责人: Shiou-Jyh Hwu
• 金额: $ 45.13万
• 依托单位: Clemson University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2003
• 资助国家: 美国
• 起止时间: 2003-11-15 至 2006-10-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0322905&HistoricalAwards=false
• 关键词: Exploratory; Synthesis; Novel; Classes; Inorganic

The objective of this research is to explore new classes of compounds that exhibit novel frameworks of electronic, magnetic and catalytic importance. The scope of the proposed project covers a broad range of fundamental inorganic chemistry, including synthesis, structure, bonding, electronic structure, magnetochemistry, and materials chemistry. The significance of this research endeavor includes: 1) discovering novel solids containing nanostructured transition metal (TM) oxide frameworks of fundamental and technological importance in, for instance, quantum computing, 2) developing, via recently implemented salt inclusion reactions, new hybrid materials exhibiting unique chemical and physical properties and 3) collaborating with researchers in various disciplines and different research institutions, including national laboratories, to facilitate in-depth structure and property correlation studies. This interdisciplinary research program will impact students in multiple ways, training and preparing them to fulfill the need for researchers with multidisciplinary backgrounds and the technical, professional, and personal skills essential to addressing the varied career demands of the future in solid state materials science.%%%The objective of this research is to explore new classes of materials that exhibit novel frameworks of electronic, magnetic and catalytic importance. A long-established area of scientific excellence in Europe, solid-state chemistry has emerged in the US in the past two decades as a field experiencing rapid growth and development. Recent advances in technology and the need for new materials in device applications have continuously driven the rapid growth of solid-state science. This proposed research is designed to nurture and train students to meet the need of globally prepared researchers who are well versed with multidisciplinary backgrounds and possess the technical, professional, and personal skills essential to addressing the varied career demands of the future. By equipping more chemists to pursue career positions in areas allied to materials chemistry, we will be enhancing the skill base in an area of vital importance to the US economy. Funding of the proposed research program will support advanced materials research as well as the long-term health, vitality, and infrastructure of each discipline, as their skills and knowledge make a considerable contribution to the high technology materials endeavors in the US. ***

这项研究的目的是探索新的化合物类别，表现出电子，磁性和催化重要性的新框架。 拟议项目的范围涵盖了广泛的基础无机化学，包括合成，结构，键合，电子结构，磁性化学和材料化学。这项研究奋进的意义包括：1）发现在例如量子计算中具有基础和技术重要性的含有纳米结构过渡金属（TM）氧化物框架的新型固体，2）通过最近实施的盐包合反应开发展现独特化学和物理性质的新型混合材料，以及3）与各种学科和不同研究机构的研究人员合作，包括国家实验室，以促进深入的结构和属性相关性研究。 这个跨学科的研究计划将以多种方式影响学生，培训和准备他们，以满足对具有多学科背景的研究人员的需求，以及解决固态材料科学未来各种职业需求所必需的技术，专业和个人技能。这项研究的目的是探索新的材料类别，表现出电子，磁性和催化重要性的新框架。 固态化学是欧洲一个历史悠久的科学卓越领域，在过去的二十年里，固态化学在美国出现，成为一个快速增长和发展的领域。 技术的最新进展和器件应用对新材料的需求不断推动着固态科学的快速发展。 这项拟议的研究旨在培养和培训学生，以满足全球准备的研究人员的需求，这些研究人员精通多学科背景，并拥有解决未来各种职业需求所必需的技术，专业和个人技能。通过装备更多的化学家在材料化学领域从事职业生涯，我们将加强对美国经济至关重要的领域的技能基础。 拟议研究计划的资金将支持先进材料研究以及每个学科的长期健康，活力和基础设施，因为他们的技能和知识为美国的高科技材料事业做出了相当大的贡献。***