Titanium-Mediated Catalytic and Stoichiometic Carbon-Carbon Bond Formations

钛介导的催化和化学计量碳-碳键的形成

• 批准号: 0416098
• 负责人: Folami Ladipo
• 金额: $ 36万
• 依托单位: University of Kentucky Research Foundation
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2004
• 资助国家: 美国
• 起止时间: 2004-07-15 至 2008-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0416098&HistoricalAwards=false
• 关键词: Titanium; Mediated; Catalytic; Stoichiometic; Carbon

This award in the Inorganic, Bioinorganic and Organometallic Chemistry program supports Professor Folami T. Ladipo at the University of Kentucky to study ancillary ligand effects in titanium chemistry in order to develop Ti(IV) electrophiles and storable Ti(II) reductants that mediate C-C bond formation. Objectives include: (1) the development of new arene-phenoxide ligands for use in ethene oligomerizations, (2) the further development of calixarene-based bis(phenolate) ligands for use in Ti(II) synthetic equivalents, and (3) Lewis-acid promoted couplings of aromatic diimines with organic carbonyls. This research is to develop new ligands to promote the polymerization of olefins. The research will also provide multidisciplinary training to undergraduate, graduate, and postdoctoral researchers. In particular, researchers from groups traditionally under-represented in science, including students from Stillman College, will be involved in high level research experiences.

这个奖项在无机，生物无机和有机化学计划支持教授Folami T。Ladipo在肯塔基州大学研究钛化学中的辅助配体效应，以开发介导C-C键形成的Ti（IV）亲电体和可储存的Ti（II）还原剂。 目标包括：（1）用于乙烯低聚的新芳烃-酚盐配体的开发，（2）用于Ti（II）合成等价物的杯芳烃基双酚盐配体的进一步开发，和（3）路易斯酸促进的芳族二亚胺与有机羰基的偶联。 本研究旨在开发新的配体来促进烯烃聚合。 该研究还将为本科生、研究生和博士后研究人员提供多学科培训。 特别是，来自传统上在科学领域代表性不足的群体的研究人员，包括斯蒂尔曼学院的学生，将参与高水平的研究经验。