Collaborative: Investigation of the Consequences of Cooperative Motion in Polymers and their Miscible Blends

协作：研究聚合物及其可混溶共混物中协作运动的后果

• 批准号: 0422062
• 负责人: Sanat Kumar
• 金额: $ 6万
• 依托单位: Rensselaer Polytechnic Institute
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2004
• 资助国家: 美国
• 起止时间: 2004-08-01 至 2007-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0422062&HistoricalAwards=false
• 关键词: Collaborative; Investigation; Consequences; Cooperative; Motion

Cooperative motion is widely accepted as being important for dynamics of glass-formingliquids, yet the length scales over which cooperative motion occurs are poorly understood.Experiments are proposed and computer simulations to address cooperative motion in polymers.While cooperative motion is thought to be important for the dynamics of all liquidsnear their glass transition, polymers o.er some unique opportunities for probing cooperativemotion. Monte Carlo and Molecular Dynamics simulations will be utilized to directly measurethe distribution of sizes and shapes of cooperatively relaxed regions, with an emphasison determining measures that can be applied to real experiments. Dielectric experimentsmeasuring the distribution of segmental relaxation times in miscible polymer blends willbe used to estimate the temperature dependence of the cooperative size, for each blendcomponent. Experiments that systematically vary polymer structure (chain length and sidegroups) will also provide less direct measures of the temperature dependence of cooperativesize in single-component polymer melts. Rheology experiments and Molecular Dynamicssimulations will explore the connection between segmental dynamics and chain dynamics, inparallel studies. This connection will allow our models for segmental dynamics in miscibleblends to be extended to predict the terminal dynamics, including the blend viscosity, withno additional parameters. The intellectual merit of this research will be an improved understandingof dynamics in polymers and their miscible blends, with particular emphasis onthe role of cooperative motion and the connection between segmental and chain dynamics. The broader impacts of the proposed research are threefold. On the one hand, the modelof miscible blend rheology will find immediate pragmatic use in the plastics industry, wherepolymer blends are vital for plastics recycling and for metals replacement in the transportationindustry. The latter enables weight to be reduced without sacrificing strength, therebysaving fuel. Simultaneously, understanding of cooperative motion will have far-reachingconsequences in developing an understanding of liquid state dynamics that goes far beyondpolymers. And finally the proposed research will create learning opportunities for graduateand undergraduate students. In addition to the involvement of both undergraduate andgraduate students in the experimental research, the PIs make extensive use of their growingknowledge of polymer physics in recruiting, advising and teaching at both the undergraduateand graduate levels.

协同运动被广泛认为是玻璃形成液体动力学的重要因素，但协同运动发生的长度尺度却知之甚少。提出了实验和计算机模拟来解决聚合物中的协同运动。虽然合作运动被认为对所有接近玻璃化转变的液体的动力学很重要，但聚合物提供了一些独特的机会来探测合作情绪。蒙特卡罗和分子动力学模拟将被用来直接测量协同松弛区域的大小和形状的分布，重点是确定可以应用于实际实验的措施。介电实验测量在混相聚合物共混物中的节段弛豫时间分布，将用于估计每个共混组分的协同尺寸的温度依赖性。系统地改变聚合物结构（链长和侧基）的实验也将提供单组分聚合物熔体中协同尺寸对温度依赖性的不太直接的测量。流变学实验和分子动力学模拟将探索片段动力学和链动力学之间的联系，并行研究。这种联系将使我们的混相共混物段动力学模型得到扩展，可以在没有额外参数的情况下预测包括共混物粘度在内的终端动力学。这项研究的智力价值将是提高对聚合物及其混相共混物动力学的理解，特别强调协同运动的作用以及节段动力学和链动力学之间的联系。拟议研究的更广泛影响有三个方面。一方面，混相共混流变学模型将在塑料工业中找到直接的实际应用，其中聚合物共混物对于塑料回收和运输工业中的金属替代至关重要。后者可以在不牺牲强度的情况下减轻重量，从而节省燃料。同时，对协同运动的理解将对发展远远超出聚合物的液态动力学的理解产生深远的影响。最后提出的研究将为研究生和本科生创造学习机会。除了让本科生和研究生参与实验研究外，pi还在本科生和研究生的招聘、指导和教学中广泛运用他们在聚合物物理学方面不断增长的知识。