NSF-Europe Materials Collaboration: Atomic Structure of Nanosize Crystalline Grains in Diamond-SiC Composites

NSF-欧洲材料合作：金刚石-SiC 复合材料中纳米晶粒的原子结构

• 批准号: 0502136
• 负责人: T. Waldek Zerda
• 金额: --
• 依托单位: Texas Christian University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-09-01 至 2009-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0502136&HistoricalAwards=false
• 关键词: NSF; Europe; Materials; Collaboration; Atomic

NON-TECHNICAL DESCRIPTION:This research program, co-funded between the Division of Materials Research and the Office of International Science and Engineering, will focus on relationship between synthesis, structure and properties of diamond-silicon carbide (SiC)composites. Diamond-based composites manufactured under high-pressure and high-temperature conditions are characterized by high hardness and very good wear resistance. How the structure and properties of the composites are influenced by inclusion of nanosize diamonds in the production protocol will be examined. Superhard diamond composites can be applied by many industries; one possible application is in oil and gas exploration where diamond composites could be used as cutting inserts in drill bits. An increase in the lifetime of drill bits will lower the cost of gas/oil drilling wells. It is difficult to assign the monetary value to the diminished risk of environmental pollution during potential blowouts by reduced frequency of drill bits replacements, but it would be substantial. This project is being carried out in collaborations with Eotvos University, Budapest, Hungary and High Pressure Research Center of Polish Academy of Sciences, Warsaw, Poland. Students will visit these institutions for extended periods of time and work under supervision of the leading Hungarian and Polish scientists. Likewise, Hungarian and Polish scientists will visit TCU and conduct high-pressure experiments at national laboratories.TECHNICAL DETAILS: The microstructure of composites can be described by characterizing diamond and silicon carbide phases in terms of their crystallite size and size distribution, and lattice strain caused by crystal defects. The most likely defects are stacking faults and interfaces between the crystallites. The emphasis is on understanding the formation mechanism of the nanostructured silicon carbide matrix, its structural and mechanical stability, and on characterization of its mechanical and physical properties. This combined approach will guide in selection of the optimum preparation procedures of precursors and technological conditions leading to sintering of superhard diamond-SiC nanocomposites. Novel methodologies of defects characterization, determination of grain sizes and atomic structure of nanocrystals from x-ray and neutron diffractograms, will be further developed and refined, and applied to characterize nanomaterials. When developed they could be used to characterize other metal, dielectric, or semiconductor nanocrystals and nanocomposites. Specifically, examination of the structures formed at the crystallite surfaces/interfaces will enable assessing chemical reactivity of these materials, and the structure of grain boundaries in nanostructured matrix and its relation to the material properties. Fundamental understanding of the atomic arrangements in nanosize crystals, especially near the interface, is absolutely necessary for further progress in nanotechnology. Supplementary information on structure of composites will be obtained from other techniques. The interdisciplinary nature of the nanotechnology-related research and proposed education activities will prepare students and young professionals for future challenges. International collaboration, integration of research activities, sharing of knowledge and practical know-how, the exchange of graduate students and post-doctoral fellows, and series of lectures offered by visiting senior researchers will offer students a new educational experience.

非技术描述：该研究计划由材料研究部和国际科学与工程办公室共同资助，将重点研究金刚石-碳化硅（SiC）复合材料的合成，结构和性能之间的关系。 在高压和高温条件下制造的金刚石基复合材料具有高硬度和非常好的耐磨性的特点。 将研究在生产方案中加入纳米金刚石对复合材料的结构和性能的影响。 超硬金刚石复合材料可以应用于许多行业;一个可能的应用是在石油和天然气勘探中，金刚石复合材料可以用作钻头中的切削刀片。 钻头寿命的增加将降低气/油井威尔斯的钻探成本。 很难将减少钻头更换频率所降低的潜在井喷期间环境污染风险的货币价值归为零，但这将是巨大的。 该项目正在与匈牙利布达佩斯的Eotvos大学和波兰华沙的波兰科学院高压研究中心合作进行。 学生将访问这些机构的时间延长，并在领先的匈牙利和波兰科学家的监督下工作。 同样，匈牙利和波兰科学家也将访问TCU，并在国家实验室进行高压实验。技术参数：复合材料的微观结构可以通过表征金刚石和碳化硅相的晶粒尺寸和尺寸分布以及晶体缺陷引起的晶格应变来描述。 最可能的缺陷是堆垛层错和微晶之间的界面。 重点是了解纳米结构碳化硅基体的形成机制，其结构和机械稳定性，以及其机械和物理性能的表征。 这种结合的方法将指导选择最佳的前体制备程序和工艺条件，导致超硬金刚石-SiC纳米复合材料的烧结。 新的缺陷表征方法，从X射线和中子衍射图的纳米晶体的晶粒尺寸和原子结构的测定，将进一步开发和完善，并应用于表征纳米材料。 当开发出来时，它们可以用来表征其他金属，电介质或半导体纳米晶体和纳米复合材料。 具体而言，在微晶表面/界面处形成的结构的检查将使得能够评估这些材料的化学反应性，以及纳米结构化基质中的晶界结构及其与材料性质的关系。 对纳米晶体中原子排列的基本理解，特别是界面附近的原子排列，对于纳米技术的进一步发展是绝对必要的。 关于复合材料结构的补充信息将从其他技术中获得。 纳米技术相关研究和拟议教育活动的跨学科性质将使学生和年轻专业人员为未来的挑战做好准备。 国际合作，研究活动的整合，知识和实用技能的共享，研究生和博士后研究员的交流，以及访问高级研究人员提供的系列讲座将为学生提供新的教育体验。