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MRI: Acquisition of an NMR Spectrometer and Upgrade of an Existing NMR Spectrometer

MRI: Acquisition of an NMR Spectrometer and Upgrade of an Existing NMR Spectrometer
MRI:购置 NMR 波谱仪并升级现有 NMR 波谱仪
批准号:
0521191
负责人:
Vincent Catalano
金额:
$0.0万
依托单位国家:
美国
项目类别:
Standard Grant
财政年份:
2005
资助国家:
美国
项目状态:
已结题
起止时间:
2005-08-01 至 2008-07-31

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中文摘要
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英文摘要
With support from the Major Research Instrumentation (MRI) Program, the Department of Chemistry at the University of Nevada in Reno will acquire a 400 MHz nuclear magnetic resonance (NMR) Spectrometer and upgrade an existing 500 MHz multinuclear NMR. This equipment will enable researchers to carry out studies on a) the design and synthesis of complex organic molecules; b) the synthesis, characterization, binding and luminescent properties of metallocryptands; c) the synthesis, structure and reactivity of organometallic complexes with emphasis on those applicable to aqueous/biphasic catalysis; d) the designed synthesis of one-dimensional benzenoid nanostructures; e) the stereochemistry of bilirubin and its carboxylate anions in organic and aqueous media by heteronuclear NMR; and f) the behavior of transition and main group metals in biological systems. Nuclear Magnetic Resonance (NMR) spectroscopy is one of the most powerful tools available to chemists for the elucidation of the structure of molecules. It is used to identify unknown substances, to characterize specific arrangements of atoms within molecules, and to study the dynamics of interactions between molecules in solution. Access to state-of-the-art NMR spectrometers is essential to chemists who are carrying out frontier research. The results from these NMR studies will have an impact in synthetic organic chemistry, nanoscience and biochemistry.
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会议论文
N-Heterocyclic Carbene Ligands as Supports for Metal-Metal Interactions: Coordination Polymers and Dimers
Purchase of a Mass Spectrometer
Metallocryptands-Inorganic Host Complexes
Extended Metal-Metal Interactions: d8 Stabilized Multiply Bonded Dimers and Oligomeric Pt-Bipyridine Springs
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