Cleavage and Formation of C-S and C-N Bonds in Heterocyclic Compounds by Homogeneous Transition Metal Complexes

均相过渡金属配合物对杂环化合物中 C-S 和 C-N 键的断裂和形成

• 批准号: 0717040
• 负责人: William Jones
• 金额: $ 40万
• 依托单位: University of Rochester
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-08-15 至 2010-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0717040&HistoricalAwards=false
• 关键词: Cleavage; Formation; Bonds; Heterocyclic; Compounds

Professor William Jones of the University of Rochester is supported by the Inorganic, Bioinorganic and Organometallic Chemistry program to develop synthetic and mechanistic aspects of reactions that cleave or form C-S or C-N bonds in heterocyclic molecules. The sulfur portion of the project is driven by hydrodesulfurization and hydrogen storage applications. Work with nitrogen is focused on C-H bond activation in arylimines as a methodology for heterocycle synthesis. The broader impacts of this project include deep hydrodesulfurization reactions of importance industrially. The program is expanding the diversity of science students through formal programs in place at the University of Rochester, and the project involves an array of interactions with high school students, undergraduates, graduate students and faculty at four year colleges.

罗彻斯特大学的William Jones教授在无机、生物无机和有机金属化学项目的支持下，研究了在杂环分子中裂解或形成C-S或C-N键的反应的合成和机理。该项目的硫部分由加氢脱硫和储氢应用驱动。与氮的工作集中在C-H键激活的芳氨酸作为杂环合成的一种方法。该项目的广泛影响包括工业上重要的深度加氢脱硫反应。该项目通过罗彻斯特大学的正式项目扩大了理科生的多样性，该项目涉及与高中生、本科生、研究生和四年制大学教师的一系列互动。