New insights into free radical reactivity via gas phase studies of radical anions

通过自由基阴离子的气相研究对自由基反应性的新见解

• 批准号: DP0986738
• 负责人: Prof Stephen Blanksby
• 金额: $ 22.12万
• 依托单位: University of Wollongong
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2009
• 资助国家: 澳大利亚
• 起止时间: 2009-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0986738
• 关键词: New; insights; into; free; radical

Free radicals are known to be critical reactive intermediates in chemical processes ranging from the formation of photochemical smog, through combustion to the onset of age-related diseases. This research increases our understanding of how free radicals react and will thus allow for more accurate prediction, and in some instances greater control, of the outcomes of chemical reactions and their health and environmental consequences. New instrumental technologies will be developed and young Australian researchers will be trained here, and with collaborators in the USA, in state-of-the-art techniques (particularly in mass spectrometry) that are essential to our emerging technology-based economy.

已知自由基在化学过程中是关键的反应性中间体，从光化学烟雾的形成到燃烧到与年龄相关的疾病的发作。这项研究增加了我们对自由基的反应方式的理解，因此将允许更准确的预测，在某些情况下，对化学反应及其健康和环境后果的结果进行了更大的控制。将开发新的乐器技术，并将在这里对年轻的澳大利亚研究人员进行培训，并与美国的合作者，最先进的技术（尤其是在质谱中），这对于我们新兴技术的经济至关重要。