Metal Complexes for Activation and Scission of Small, Multiply-Bonded Molecules

用于活化和裂解小多重键分子的金属配合物

• 批准号: DP0986529
• 负责人: Em/Prof Robert Stranger
• 金额: $ 22.85万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2009
• 资助国家: 澳大利亚
• 起止时间: 2009-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0986529
• 关键词: Metal; Complexes; Activation; Scission; Small

The immediate outcome of this work is a series of metal complexes capable of selectively cleaving the strong bonds present in a number of small molecules of chemical importance. This will have a significant impact on industry by providing cheaper and safer alternatives to currently expensive and hazardous processes for producing nitrogen and phosphorus containing compounds esential to the chemical and agricultural industries. It will also greatly benefit the chemical community by providing novel routes to constructing metal complexes with unusual and exotic ligands. These outcomes will lead to new consumer products and potential downstream applications such as nitric oxide/nitrogen dioxide converters and carbon dioxide emission controls.

这项工作的直接结果是一系列的金属络合物，能够选择性地裂解许多化学意义的小分子中的强键。这将对工业产生重大影响，通过为目前昂贵且危险的过程提供更便宜，更安全的替代品，用于生产含有化合物和农业行业的化合物的氮和磷。通过为用异常和异国配体构造金属配合物的新途径，这也将极大地使化学界受益。这些结果将导致新的消费产品和潜在的下游应用，例如一氧化氮/二氧化氮转化剂和二氧化碳发射控制。