Metal Complexes for Activation and Scission of Small, Multiply-Bonded Molecules

用于活化和裂解小多重键分子的金属配合物

• 批准号: DP0986529
• 负责人: Em/Prof Robert Stranger
• 金额: $ 22.85万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2009
• 资助国家: 澳大利亚
• 起止时间: 2009-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0986529
• 关键词: Metal; Complexes; Activation; Scission; Small

The immediate outcome of this work is a series of metal complexes capable of selectively cleaving the strong bonds present in a number of small molecules of chemical importance. This will have a significant impact on industry by providing cheaper and safer alternatives to currently expensive and hazardous processes for producing nitrogen and phosphorus containing compounds esential to the chemical and agricultural industries. It will also greatly benefit the chemical community by providing novel routes to constructing metal complexes with unusual and exotic ligands. These outcomes will lead to new consumer products and potential downstream applications such as nitric oxide/nitrogen dioxide converters and carbon dioxide emission controls.

这项工作的直接成果是一系列金属络合物，能够选择性地裂解存在于许多具有化学重要性的小分子中的强键。这将对工业产生重大影响，为目前昂贵且危险的生产化学和农业工业必需的含氮和磷化合物的工艺提供更便宜、更安全的替代方案。它也将大大有利于化学界提供新的路线，以构建金属配合物与不寻常的和外来的配体。这些成果将导致新的消费产品和潜在的下游应用，如一氧化氮/二氧化氮转换器和二氧化碳排放控制。