Metal Complexes for Activation and Scission of Small, Multiply-Bonded Molecules

用于活化和裂解小多重键分子的金属配合物

• 批准号: DP0663045
• 负责人: Em/Prof Robert Stranger
• 金额: $ 31.85万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2006
• 资助国家: 澳大利亚
• 起止时间: 2006-01-01 至 2009-01-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0663045
• 关键词: Metal; Complexes; Activation; Scission; Small

The immediate outcome of this work is a series of new metal complexes capable of selectively cleaving the strong bonds present in a number of small molecules of industrial and synthetic importance. These outcomes will have a significant impact on the development of both novel transition metal systems for synthetic chemistry and new industrial procedures for the activation and cleavage of multiply-bonded molecules such as molecular nitrogen and carbon dioxide. They will lead to new consumer products, better methods of production, and potential downstream applications such as nitric oxide/nitrogen dioxide converters and carbon dioxide emission controls.

这项工作的直接成果是一系列新的金属配合物，能够选择性地裂解存在于许多具有工业和合成重要性的小分子中的强键。这些成果将对开发用于合成化学的新型过渡金属系统和用于活化和裂解多键分子（如分子氮和二氧化碳）的新工业程序产生重大影响。它们将带来新的消费品、更好的生产方法以及潜在的下游应用，如一氧化氮/二氧化氮转化器和二氧化碳排放控制。