Activation and Scission of Small Molecules using Three-Coordinate Metal Complexes

使用三配位金属配合物激活和裂解小分子

• 批准号: DP0342577
• 负责人: Em/Prof Robert Stranger
• 金额: $ 17.8万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2003
• 资助国家: 澳大利亚
• 起止时间: 2003-01-01 至 2005-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP0342577
• 关键词: Activation; Scission; Small; Molecules; using

Chemists have long admired the ease with which such fundamental molecules as nitrogen, oxygen and carbon dioxide are processed in biological systems under mild conditions in contrast to existing industrial processes such as nitrogen 'fixation' which require drastic temperatures and pressures. Our project addresses this inbalance by using powerful computational methods to design highly-tuned chemical systems based on three-coordinate metal complexes which are specific for the activation and scission of important small molecules possessing multiple bonds.

化学家长期以来一直钦佩这种基本分子，如氮，氧和二氧化碳在温和条件下在生物系统中处理的容易程度，与现有的工业过程相比，如氮“固定”，需要剧烈的温度和压力。我们的项目通过使用强大的计算方法来设计基于三配位金属配合物的高度调整的化学系统来解决这种不平衡问题，这些配合物专门用于具有多键的重要小分子的激活和断裂。