In-situ Synchrotron X-ray Diffraction Study of Quartz Deformation

石英变形的原位同步加速器 X 射线衍射研究

• 批准号: 0838579
• 负责人: Pamela Burnley
• 金额: $ 30.53万
• 依托单位: University of Nevada Las Vegas
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-09-01 至 2013-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0838579&HistoricalAwards=false
• 关键词: situ; Synchrotron; ray; Diffraction; Study

This award is funded under the American Recovery and Reinvestment Act of2009 (Public Law 111-5).Non-technical explanation:The ability to predict the response of crystalline solids to forces thatcause them to change shape, or in other words deform, is important in manyareas including materials engineering, metallurgy and geoscience and hasapplications to problems ranging from metals forming to mountain building. This research project will investigate the deformation behavior ofquartzite, a common quartz-bearing rock, at the temperatures and pressuresrelevant to the earth's interior. We will use a combination of in-situsynchrotron x-ray diffraction, computer based simulations and sampleanalysis to study the behavior of specific groups of crystals within therock which will improve our understanding of how the behavior of groups ofcrystals within a rock integrate to produce the overall behavior of therock. Our results will be most useful in understanding geologicalprocesses such as those that produce mountains or determine where inEarth's crust, earthquakes occur. However, because the deformationmechanisms that allow quartz crystals to deform are the same as those thatoperate in metals and ceramics, we anticipate that our results will alsoshed light on more general questions that have applications to a range ofengineering problems. The majority of the funding requested for thisproject will support the education of young scientists includingundergraduate, graduate and post-graduate scholars by supporting them asthey participate in cutting edge research.Technical explanation:This project will use in-situ synchrotron x-ray diffraction from highpressure, high temperature deformation experiments on quartz combined withelastic plastic self consistent modeling and careful examination of samplemicrostructures to learn about the distribution of stress between grainpopulations during deformation. The experiments are designed to allow usto examine the relative roles of various deformation mechanisms andgrain-grain interactions in generating the overall rheological behavior ofpolycrystalline quartz. In addition, the combination of microstructuralanalysis with synchrotron diffraction observations will add a great dealto the understanding and interpretation of diffraction data gathered fromhigh pressure deformation experiments. Therefore the results from thisstudy will have implications for and applications to deformation studiesof other earth materials made with large volume high pressure apparatus,as well as ultrahigh pressure deformation studies in the diamond anvilcell (DAC) that utilize the same type of diffraction data. The resultswill also have implications for neutron and x-ray diffraction studies ofengineering ceramics and metals.

非技术性解释：预测晶体固体对导致其改变形状的力的反应，或者换句话说，变形的能力，在许多领域都很重要，包括材料工程，冶金和地球科学，并应用于从金属形成到造山的问题。本研究计画将探讨石英岩，一种常见的含石英岩石，在与地球内部相关的温度和压力下的变形行为。我们将使用同步辐射X射线衍射，计算机模拟和样品分析的组合来研究岩石中特定晶体组的行为，这将提高我们对岩石中晶体组的行为如何整合以产生岩石整体行为的理解。 我们的研究结果将是最有用的了解地质过程，如那些产生山脉或确定在地壳，地震发生。 然而，由于允许石英晶体变形的变形机制与金属和陶瓷中的变形机制相同，我们预计我们的结果也将有助于解决更普遍的问题，这些问题可应用于一系列工程问题。 该项目的大部分资金将用于支持年轻科学家的教育，包括本科生，研究生和研究生学者，支持他们参与前沿研究。技术说明：该项目将使用高压，高温变形石英实验的原位同步X射线衍射结合弹塑性自洽建模和样品微观结构的仔细检查，以了解变形过程中晶粒之间的应力分布。 实验的目的是让我们检查各种变形机制和颗粒-颗粒相互作用的相对作用，在产生的整体流变行为的多晶石英。 此外，显微结构分析与同步辐射衍射观测的结合将大大有助于理解和解释高压变形实验所收集的衍射数据。 因此，从这项研究的结果将有影响和应用到变形研究的其他地球材料与大体积的高压设备，以及在金刚石砧（DAC）的超高压变形研究，利用相同类型的衍射数据。 这些结果也将对工程陶瓷和金属的中子和x射线衍射研究产生影响。