Design of Microwave Selective Oygen Atom Transfer Reagents for Controlled Metal Oxide Formation

用于控制金属氧化物形成的微波选择性氧原子转移试剂的设计

• 批准号: 0911080
• 负责人: Geoffrey Strouse
• 金额: $ 43.5万
• 依托单位: Florida State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-09-01 至 2013-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0911080&HistoricalAwards=false
• 关键词: Design; Microwave; Selective; Oygen; Atom

In this project funded by the Inorganic, Bioinorganic, and Organometallic Chemistry Program of the Chemistry Division, Geoffrey Strouse and Albert Stiegman of Florida State University will develop oxygen atom transfer agents that absorb microwave radiation. With the help of computational methods the PIs will estimate the microwave absorption cross section for a range of compounds, and then prepare and examine them in test chemical reactions. Promising reagents will then be used in the synthesis of metal oxide nanophase materials, and for this project the PIs will target zirconium oxide, zinc oxide and gallium oxide. This method could potentially enable unprecedented control over nanocrystal growth that would have transformative impacts on nanomaterials related applications. The PIs will also continue to promote research experiences for undergraduate students and will bring high school students to his laboratory to gain research experience as interns.

在这个由化学部无机、生物无机和金属有机化学项目资助的项目中，佛罗里达州立大学的杰弗里·斯特劳斯和阿尔伯特·斯蒂格曼将开发吸收微波辐射的氧原子转移剂。在计算方法的帮助下，PI将估计一系列化合物的微波吸收截面，然后准备并在测试化学反应中进行检验。然后，有希望的试剂将被用于合成金属氧化物纳米材料，在这个项目中，PI将针对氧化锆、氧化锌和氧化镓。这种方法可能实现对纳米晶体生长的前所未有的控制，这将对纳米材料的相关应用产生革命性的影响。PIS还将继续为本科生推广研究经验，并将把高中生带到他的实验室，作为实习生获得研究经验。