GOALI: Novel Low-Polluting Collagen-Alkali Silicate

目标：新型低污染胶原蛋白-碱硅酸盐

• 批准号: 0927967
• 负责人: Fred Cannon
• 金额: $ 33.77万
• 依托单位: Pennsylvania State Univ University Park
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-08-15 至 2012-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0927967&HistoricalAwards=false
• 关键词: GOALI; Novel; Low; Polluting; Collagen

This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5). The research objective of this Grant Opportunity for Academic Liaison with Industry (GOALI) award is to devise a low volatile organic carbon (VOC) core binder that is comprised of a collagen-alkali silicate hybrid. The use of these binders can save energy and money in foundry processes, while diminishing their petroleum dependence. We aim to replace conventional petroleum-based binders, which cause significant volatile organic carbon pollution. Collagen is the triple-helical protein structure that comprises animal tendons and hides; and collagen has the tensile strength of steel. Collagen releases 15-25% as much VOC pollution as do phenolic urethanes in a foundry setting; and silicates release negligible amounts of VOCs. Together, collagen-alkali silicate hybrids favorably offer the promise of good thermal integrity, high tensile strength, good casting quality, and good shake-out, as discerned from preliminary results. To accomplish the research objectives, we will prepare collagen-alkali silicate bindered cores with an array of collagen-to-silicate proportions, mixing protocols, and curing processes. Per foundry criteria, we will appraise these relative to their resistance against molten iron erosion; and their tensile strength, hardness, shakeout propensity, and thermal integrity. Also, per fundamentals, we will characterize bonding by infrared analysis, nuclear magnetic resonance, and electron microscopy. These fundamental characterizations will steer the collagen-alkali silicate chemistry and processing protocol, so as to select the most favorable binder system.The expected benefits of this research will be to initiate a transformative rewriting of adhesives chemistry based on new metrics. The new metrics are to pursue US petrochemical independence with environmentally benign manufacturing, while devising sustainable products from bio-resources. This research will also expand fundamentals of adhesives and nitrogen chemistry; thermal effects on collagen and alkali silicates; curing kinetics; waterproofing; and environmental and industrial engineering. In addition to these important impacts this GOALI project team will conduct full-scale demonstrations of these collagen-alkali silicate binders at the HMAC-Lawrenceville, PA foundry, providing tremendous industrial value for the community.

该奖项是根据2009年美国复苏和再投资法案（公法111-5）资助的。这项学术与工业联络资助机会（GOALI）奖的研究目标是设计一种由胶原蛋白-碱硅酸盐混合物组成的低挥发性有机碳（VOC）核心粘合剂。使用这些粘合剂可以在铸造过程中节省能源和金钱，同时减少对石油的依赖。我们的目标是取代传统的石油基粘合剂，这种粘合剂会造成严重的挥发性有机碳污染。胶原蛋白是由动物肌腱和兽皮组成的三螺旋蛋白结构；胶原蛋白具有钢的抗拉强度。在铸造环境中，胶原蛋白释放的VOC污染是酚醛聚氨酯的15-25%；和硅酸盐释放的挥发性有机化合物可以忽略不计。从初步结果中可以看出，胶原蛋白-碱硅酸盐混合物具有良好的热完整性、高拉伸强度、良好的铸造质量和良好的脱砂效果。为了完成研究目标，我们将用一系列胶原-碱硅酸盐比例、混合方案和固化工艺制备胶原-碱硅酸盐结合岩心。根据铸造标准，我们将评估这些相对于它们对铁水侵蚀的抵抗力；以及它们的抗拉强度、硬度、脱砂倾向和热完整性。此外，根据基本原理，我们将通过红外分析，核磁共振和电子显微镜来表征键合。这些基本表征将指导胶原-碱硅酸盐化学和加工方案，从而选择最合适的粘结剂体系。这项研究的预期好处将是基于新指标启动粘合剂化学的变革性重写。新的衡量标准是，在利用生物资源设计可持续产品的同时，通过无害环境的制造，追求美国石化行业的独立性。这项研究还将扩展粘合剂和氮化学的基础知识；热效应对胶原蛋白和碱硅酸盐的影响；固化动力学;防水;以及环境和工业工程。除了这些重要影响之外，GOALI项目团队还将在宾夕法尼亚州HMAC-Lawrenceville铸造厂对这些胶原-碱硅酸盐粘合剂进行全面演示，为社区提供巨大的工业价值。