Bifunctional dehydrocoupling of inorganic substrates: Scope and mechanism

无机基质的双功能脱氢偶联：范围和机制

• 批准号: 206445449
• 负责人: Professor Dr. Sven Schneider
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 财政年份: 2011
• 资助国家: 德国
• 起止时间: 2010-12-31 至 2014-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/206445449?language=en
• 关键词: Bifunctional; dehydrocoupling; inorganic; substrates; Scope

The mechanism of PNP ruthenium catalysed borane-amine dehydrocoupling will be probed by means of kinetics and stereoselective polyaminoborane synthesis with the goal to establish synthetic pathways towards novel inorganic polymers. These materials will be examined for potential applications in enantioselective hydrogenation of prochiral organic functional groups with polar multiple bonds and the synthesis of ternary III/V semiconductor materials with tailored band gaps.

本论文将从动力学和立体选择性的角度探讨PNP Ru催化的硼烷-胺脱氢偶联反应的机理，旨在为新型无机聚合物的合成开辟新的途径。这些材料将在具有极性多键的前手性有机官能团的对映选择性氢化和合成具有定制带隙的三元III/V半导体材料方面得到潜在的应用。

项目成果

The mechanism of borane-amine dehydrocoupling with bifunctional ruthenium catalysts.

• DOI: 10.1021/ja311092c
• 发表时间: 2013-09
• 期刊: Journal of the American Chemical Society
• 影响因子: 15
• 作者: A. Marziale;A. Friedrich;I. Klopsch;M. Drees;V. R. Celinski;J. Schmedt auf der Günne;S. Schneider

Synthesis and structure of six-coordinate iron borohydride complexes supported by PNP ligands.

PNP配体支持的六配位硼氢化铁配合物的合成与结构

• DOI: 10.1021/ic402762v
• 发表时间: 2014
• 期刊: Inorganic chemistry
• 影响因子: 4.6
• 作者: I. Koehne;T. J. Schmeier;E. A. Bielinski;C. J. Pan;W. H. Bernskoetter;C. Würtele;M. K. Takase;N. Hazari;S. Schneider
• 通讯作者: S. Schneider

Highly Active Iron Catalyst for Ammonia Borane Dehydrocoupling at Room Temperature

• DOI: 10.1021/acscatal.5b02406
• 发表时间: 2015-12-01
• 期刊: ACS CATALYSIS
• 影响因子: 12.9
• 作者: Glueer, Arne;Foerster, Moritz;Schneidert, Sven
• 通讯作者: Schneidert, Sven