CAREER: Elucidating the Structural-Functional Relationship of Photoelectrochemically Active Molecular Multilayers

来自伦斯勒理工学院的Peter H. Dinolfo教授获得了美国国家科学基金会化学分部化学结构、动力学和机制B项目的CAREER奖，研究电极界面上分子供体-受体系统的光电化学性质。设计用于特定电子、光子或电光应用的多层材料需要对薄膜及其各自构建块的结构-功能关系有准确的了解。利用PI实验室开发的一种新的分层组装技术，由光谱调谐的有机和无机发色团组成的多层膜将以供体-受体结构组装在电极表面上。光谱学和电化学方法将应用于修饰的衬底，以阐明发色团层之间能量和电子转移过程的机制和效率。然后，这些信息将与多层薄膜上的结构数据相关联，以确定创建用于p型染料敏化半导体太阳能电池的高效分子基光收集阵列的最佳条件。开发适应性的方法来化学修饰电极和半导体表面具有层次的分子结构，并了解分子成分之间发生的光物理过程对人工光合作用领域至关重要。这项研究将有助于制定必要的设计原则，以提高下一代分子太阳能电池和人工光合装置的效率。该项目还将为材料化学跨学科领域的本科生和研究生提供培训。此外，为了刺激和鼓励年轻学生考虑在STEM领域之一的职业生涯，PI将为当地高中生组织和举办为期一周的研讨会。这些学生将在伦斯勒理工学院的PI实验室参加一些实践活动，这些活动旨在强调太阳能转换和人工光合作用的一些基本化学方面。

Professor Peter H. Dinolfo from Rensselaer Polytechnic Institute is supported by a CAREER award from the Chemical Structure, Dynamics, and Mechanisms B program in the NSF Chemistry Division to study the photo- and electro-chemical properties of molecular donor-acceptor systems at electrode interfaces. The design of multilayer materials for specific electronic, photonic, or electro-optical applications requires an accurate knowledge of the structural-functional relationships of the films and their respective building blocks. Using a new layer-by-layer assembly technique developed in the PI's laboratory, multilayer films comprised of spectrally-tuned organic and inorganic chromophores will be assembled in donor-acceptor configurations on electrode surfaces. Spectroscopic and electrochemical methods will be applied to the modified substrates to elucidate the mechanisms and efficiency of energy and electron transfer processes between chromophore layers. This information will then be correlated with structural data on the multilayer thin films to determine the optimal conditions for creating efficient molecular-based light harvesting arrays for use in p-type dye-sensitized semiconductor solar cells.Developing adaptable methods to chemically modify electrode and semiconductor surfaces with hierarchical molecular structures and understanding the photophysical processes occurring amongst the molecular constituents is of central importance to the field of artificial photosynthesis. This research will help formulate the design principles necessary to improve the efficiency of next generation molecular based solar cells and artificial photosynthetic devices. The project will also provide training for a diverse group of undergraduate and graduate students in the interdisciplinary field of materials chemistry. Additionally, in an effort to stimulate and encourage young students to consider a career in one of the STEM fields, the PI will organize and run a week-long workshop for local high school students. These students will participate in several hands-on activities in the PI's laboratory at Rensselaer Polytechnic Institute that are designed to highlight some of the basic chemical aspects of solar energy conversion and artificial photosynthesis.