Indenofluorenes and Related Structures: Syntheses, Properties and Emerging Materials Applications

茚并芴及相关结构：合成、性质和新兴材料应用

• 批准号: 1301485
• 负责人: Michael Haley
• 金额: $ 44.39万
• 依托单位: University of Oregon Eugene
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2013
• 资助国家: 美国
• 起止时间: 2013-07-01 至 2016-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1301485&HistoricalAwards=false
• 关键词: Indenofluorenes; Related; Structures; Syntheses; Properties

With the support of this award from the Chemical Synthesis Program of the Division of Chemistry, Professor Michael Haley of the Department of Chemistry at the University of Oregon will prepare and study molecules based on or inspired by the indenofluorene skeleton to answer fundamental scientific questions as well as to explore their materials properties. The Haley research program will develop facile synthetic methods for the assembly of these strongly electron-accepting molecules. Once in hand, the Haley group will examine the optical and electronic properties of all new molecular scaffolds with an emphasis towards organic field effect transistor (OFET) and organic photovoltaic (OPV) applications and use in devices. The study of such molecules answers fundamental questions regarding the electronic structure and properties of non-benzenoid organic materials.The molecules developed in these studies present opportunities for practical applications, particularly in the area of nanotechnology and low-cost electronics. Moreover, this project serves as an excellent training ground for graduate and undergraduate researchers in fundamental and applied chemical synthesis. The studies will provide the researchers with broad experience in organic synthesis, computational chemistry, x-ray crystallography, and the interplay between electronic structure and molecular architecture. The broader impacts of this program include industrial internships of graduate students at local and regional companies and national labs, the exchange of graduate students with those of foreign collaborators in Germany, Denmark, and Japan, the hosting of extended stays of visiting scientists including professors from PUIs, and continued substantial involvement of undergraduates in state-of-the-art chemical research via programs which promote the participation of underrepresented groups.

在化学系化学综合计划的支持下，俄勒冈大学化学系的迈克尔·海莉教授将基于或启发Indenofluorene骨架的迈克尔·海莉（Michael Haley），以准备和研究分子，以回答基本科学问题以及探索其材料的基本科学问题。 Haley Research计划将开发可容纳这些强烈电子受感受的分子的容易合成方法。一旦掌握，海利组将检查所有新分子支架的光学和电子特性，重点是有机场效应晶体管（OFET）和有机光伏（OPV）（OPV）应用，并在设备中使用。此类分子的研究回答了有关非偶氮材料材料的电子结构和特性的基本问题。这些研究中开发的分子为实际应用提供了机会，尤其是在纳米技术和低成本电子学领域。 此外，该项目是基础化学和应用化学合成研究生和本科研究人员的绝佳培训场。这些研究将为研究人员提供广泛的有机合成，计算化学，X射线晶体学以及电子结构与分子结构之间的相互作用。该计划的更广泛的影响包括在当地和地区公司以及国家实验室的研究生的工业实习，与德国，丹麦和日本的外国合作者的研究生交流，在包括PUI的教授在内的访问科学家的长期住宿，以及继续在整个阶段的研究中，参与者促进了该计划的较低的访问者，这些访问的科学家持续了很多。