Indenofluorenes and Related Structures: Syntheses, Properties and Emerging Materials Applications

茚并芴及相关结构：合成、性质和新兴材料应用

• 批准号: 1301485
• 负责人: Michael Haley
• 金额: $ 44.39万
• 依托单位: University of Oregon Eugene
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2013
• 资助国家: 美国
• 起止时间: 2013-07-01 至 2016-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1301485&HistoricalAwards=false
• 关键词: Indenofluorenes; Related; Structures; Syntheses; Properties

With the support of this award from the Chemical Synthesis Program of the Division of Chemistry, Professor Michael Haley of the Department of Chemistry at the University of Oregon will prepare and study molecules based on or inspired by the indenofluorene skeleton to answer fundamental scientific questions as well as to explore their materials properties. The Haley research program will develop facile synthetic methods for the assembly of these strongly electron-accepting molecules. Once in hand, the Haley group will examine the optical and electronic properties of all new molecular scaffolds with an emphasis towards organic field effect transistor (OFET) and organic photovoltaic (OPV) applications and use in devices. The study of such molecules answers fundamental questions regarding the electronic structure and properties of non-benzenoid organic materials.The molecules developed in these studies present opportunities for practical applications, particularly in the area of nanotechnology and low-cost electronics. Moreover, this project serves as an excellent training ground for graduate and undergraduate researchers in fundamental and applied chemical synthesis. The studies will provide the researchers with broad experience in organic synthesis, computational chemistry, x-ray crystallography, and the interplay between electronic structure and molecular architecture. The broader impacts of this program include industrial internships of graduate students at local and regional companies and national labs, the exchange of graduate students with those of foreign collaborators in Germany, Denmark, and Japan, the hosting of extended stays of visiting scientists including professors from PUIs, and continued substantial involvement of undergraduates in state-of-the-art chemical research via programs which promote the participation of underrepresented groups.

在化学系化学合成计划的这一奖项的支持下，俄勒冈大学化学系的Michael Haley教授将制备和研究基于吲哚骨架或受其启发的分子，以回答基本的科学问题以及探索其材料性质。黑利研究计划将开发简便的合成方法来组装这些强烈接受电子的分子。一旦拿到手，Haley小组将检查所有新的分子支架的光学和电学性质，重点是有机场效应晶体管(OFET)和有机光伏(OPV)的应用和在设备中的使用。这些分子的研究回答了有关非苯类有机材料的电子结构和性质的基本问题。这些研究中开发的分子为实际应用提供了机会，特别是在纳米技术和低成本电子领域。此外，该项目还为基础和应用化学合成方面的研究生和本科生研究人员提供了一个极好的培训基地。这些研究将为研究人员提供在有机合成、计算化学、X射线结晶学以及电子结构和分子结构之间的相互作用方面的广泛经验。该计划的更广泛影响包括在当地和地区公司以及国家实验室的研究生的工业实习，与德国、丹麦和日本的外国合作者交换研究生，接待包括PUI教授在内的来访科学家的长期逗留，以及通过促进代表不足的群体参与的计划，继续让本科生大量参与最先进的化学研究。